[2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes

Pavel P. Chapala, Maxim V. Bermeshev, Valentin G. Lakhtin, Alexander M. Genaev, Alexander N. Tavtorkin, Eugene Sh. Finkelshtein

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

[2σ + 2σ + 2π]-Cycloaddition of quadricyclane to trissilylated ethenes Cl3 – nMenSiCH=CSiMenCl3 – n(SiMe3 – nCln) (n = 1, 2) at 95°C affords 3,3,4-trissilylated exo-tricyclo[4.2.1.02,5]non-7-enes. Tetrakis(trichlorosilyl)ethene does not react with quadricyclane.
Original languageEnglish GB
Pages (from-to)344-345
Number of pages2
JournalMendeleev Communications
Volume25
Issue number5
DOIs
StatePublished - 2015
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (all)

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