2-(Trialkoxysilylalkylthio)ethyl vinyl sulfides

N. N. Vlasova; F. P. Kletsko; S. V. Amosova; M. V. Sigalov; B. A. Trofimov; M. G. Voronkov

doi:10.1007/BF00921523

2-(Trialkoxysilylalkylthio)ethyl vinyl sulfides

N. N. Vlasova, F. P. Kletsko, S. V. Amosova, M. V. Sigalov, B. A. Trofimov, M. G. Voronkov

Research output: Contribution to journal › Article › peer-review

Abstract

Trialkoxysilylalkanethiols (CH₃O)₃Si(CH₂)_nSH (n=1-3) react with divinyl sulfide at 100-110° to give 2-(trialkoxysilylalkylthio)ethyl vinyl sulfides (CH₃O)₃Si(CH₂)_nS (CH₂)₂SCH=CH₂ in high yield. The reactivity of the trialkoxysilylalkanethiols decreases with increase in the number of CH₂ groups between the S and Si atoms. A second molecule of the organosilicon thiol acids adds with difficulty to divinyl sulfide to give the diadduct.

Original language	English
Pages (from-to)	174-176
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	26
Issue number	1
DOIs	https://doi.org/10.1007/BF00921523
State	Published - 1 Jan 1977
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "2-(Trialkoxysilylalkylthio)ethyl vinyl sulfides",

abstract = "Trialkoxysilylalkanethiols (CH3O)3Si(CH2)nSH (n=1-3) react with divinyl sulfide at 100-110° to give 2-(trialkoxysilylalkylthio)ethyl vinyl sulfides (CH3O)3Si(CH2)nS (CH2)2SCH=CH2 in high yield. The reactivity of the trialkoxysilylalkanethiols decreases with increase in the number of CH2 groups between the S and Si atoms. A second molecule of the organosilicon thiol acids adds with difficulty to divinyl sulfide to give the diadduct.",

author = "Vlasova, {N. N.} and Kletsko, {F. P.} and Amosova, {S. V.} and Sigalov, {M. V.} and Trofimov, {B. A.} and Voronkov, {M. G.}",

year = "1977",

month = jan,

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doi = "10.1007/BF00921523",

language = "English",

volume = "26",

pages = "174--176",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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number = "1",

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TY - JOUR

T1 - 2-(Trialkoxysilylalkylthio)ethyl vinyl sulfides

AU - Vlasova, N. N.

AU - Kletsko, F. P.

AU - Amosova, S. V.

AU - Sigalov, M. V.

AU - Trofimov, B. A.

AU - Voronkov, M. G.

PY - 1977/1/1

Y1 - 1977/1/1

N2 - Trialkoxysilylalkanethiols (CH3O)3Si(CH2)nSH (n=1-3) react with divinyl sulfide at 100-110° to give 2-(trialkoxysilylalkylthio)ethyl vinyl sulfides (CH3O)3Si(CH2)nS (CH2)2SCH=CH2 in high yield. The reactivity of the trialkoxysilylalkanethiols decreases with increase in the number of CH2 groups between the S and Si atoms. A second molecule of the organosilicon thiol acids adds with difficulty to divinyl sulfide to give the diadduct.

AB - Trialkoxysilylalkanethiols (CH3O)3Si(CH2)nSH (n=1-3) react with divinyl sulfide at 100-110° to give 2-(trialkoxysilylalkylthio)ethyl vinyl sulfides (CH3O)3Si(CH2)nS (CH2)2SCH=CH2 in high yield. The reactivity of the trialkoxysilylalkanethiols decreases with increase in the number of CH2 groups between the S and Si atoms. A second molecule of the organosilicon thiol acids adds with difficulty to divinyl sulfide to give the diadduct.

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U2 - 10.1007/BF00921523

DO - 10.1007/BF00921523

M3 - Article

AN - SCOPUS:34250292763

SN - 0568-5230

VL - 26

SP - 174

EP - 176

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 1

ER -

2-(Trialkoxysilylalkylthio)ethyl vinyl sulfides

Abstract

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