2,6-bisorganylsulfonyl-1,4-dithiafulvenes

A. N. Mirskova; G. G. Levkovskaya; A. V. Martynov; I. D. Kalikhman; M. G. Voronkov

doi:10.1007/BF00961763

2,6-bisorganylsulfonyl-1,4-dithiafulvenes

A. N. Mirskova, G. G. Levkovskaya, A. V. Martynov, I. D. Kalikhman, M. G. Voronkov

Research output: Contribution to journal › Article › peer-review

Abstract

The reactions of organyl β,β-dichlorovinyl sulfones with sulfur-containing nucleophiles, viz., sodium sulfide and salts of alkylxanthic acids, have been studied. A preparative method for synthesizing heretofore unknown 2,6-bisorganylsulfonyl-1,4-dithiafulvenes from organyl β,β-dichlorovinyl sulfones and Na₂S·9H₂O in ethanol has been proposed. The isomeric composition of the compounds synthesized was studied, and their easy isomerization in an acidic medium has been established.

Original language	English
Pages (from-to)	281-285
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	29
Issue number	2
DOIs	https://doi.org/10.1007/BF00961763
State	Published - 1 Jan 1980
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00961763

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title = "2,6-bisorganylsulfonyl-1,4-dithiafulvenes",

abstract = "The reactions of organyl β,β-dichlorovinyl sulfones with sulfur-containing nucleophiles, viz., sodium sulfide and salts of alkylxanthic acids, have been studied. A preparative method for synthesizing heretofore unknown 2,6-bisorganylsulfonyl-1,4-dithiafulvenes from organyl β,β-dichlorovinyl sulfones and Na2S·9H2O in ethanol has been proposed. The isomeric composition of the compounds synthesized was studied, and their easy isomerization in an acidic medium has been established.",

author = "Mirskova, {A. N.} and Levkovskaya, {G. G.} and Martynov, {A. V.} and Kalikhman, {I. D.} and Voronkov, {M. G.}",

year = "1980",

month = jan,

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doi = "10.1007/BF00961763",

language = "English",

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journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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T1 - 2,6-bisorganylsulfonyl-1,4-dithiafulvenes

AU - Mirskova, A. N.

AU - Levkovskaya, G. G.

AU - Martynov, A. V.

AU - Kalikhman, I. D.

AU - Voronkov, M. G.

PY - 1980/1/1

Y1 - 1980/1/1

N2 - The reactions of organyl β,β-dichlorovinyl sulfones with sulfur-containing nucleophiles, viz., sodium sulfide and salts of alkylxanthic acids, have been studied. A preparative method for synthesizing heretofore unknown 2,6-bisorganylsulfonyl-1,4-dithiafulvenes from organyl β,β-dichlorovinyl sulfones and Na2S·9H2O in ethanol has been proposed. The isomeric composition of the compounds synthesized was studied, and their easy isomerization in an acidic medium has been established.

AB - The reactions of organyl β,β-dichlorovinyl sulfones with sulfur-containing nucleophiles, viz., sodium sulfide and salts of alkylxanthic acids, have been studied. A preparative method for synthesizing heretofore unknown 2,6-bisorganylsulfonyl-1,4-dithiafulvenes from organyl β,β-dichlorovinyl sulfones and Na2S·9H2O in ethanol has been proposed. The isomeric composition of the compounds synthesized was studied, and their easy isomerization in an acidic medium has been established.

UR - http://www.scopus.com/inward/record.url?scp=34250246621&partnerID=8YFLogxK

U2 - 10.1007/BF00961763

DO - 10.1007/BF00961763

M3 - Article

AN - SCOPUS:34250246621

SN - 0568-5230

VL - 29

SP - 281

EP - 285

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 2

ER -

2,6-bisorganylsulfonyl-1,4-dithiafulvenes

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