2,6-bisorganylsulfonyl-1,4-dithiafulvenes

A. N. Mirskova, G. G. Levkovskaya, A. V. Martynov, I. D. Kalikhman, M. G. Voronkov

Research output: Contribution to journalArticlepeer-review

Abstract

The reactions of organyl β,β-dichlorovinyl sulfones with sulfur-containing nucleophiles, viz., sodium sulfide and salts of alkylxanthic acids, have been studied. A preparative method for synthesizing heretofore unknown 2,6-bisorganylsulfonyl-1,4-dithiafulvenes from organyl β,β-dichlorovinyl sulfones and Na2S·9H2O in ethanol has been proposed. The isomeric composition of the compounds synthesized was studied, and their easy isomerization in an acidic medium has been established.

Original languageEnglish
Pages (from-to)281-285
Number of pages5
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume29
Issue number2
DOIs
StatePublished - 1 Feb 1980
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry

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