(2E)-1-Phenyl-2-[1-(2-phenylprop-2-en-1-yl)pyrrolidin-2-ylidene]ethanone

Lee G. Madeley; Garreth L. Morgans; Andreas Lemmerer; Joseph P. Michael

doi:10.1107/S1600536812044443

(2E)-1-Phenyl-2-[1-(2-phenylprop-2-en-1-yl)pyrrolidin-2-ylidene]ethanone

Lee G. Madeley
, Garreth L. Morgans
, Andreas Lemmerer
, Joseph P. Michael

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, C21H21NO, is a vinylogous amide (enaminone) produced by reaction of 1-(2-phenylprop-2-en-1-yl)pyrrolidine-2-thione with phenacyl bromide. In the molecule, the phenyl rings are twisted from the mean plane of the pyrrolidine ring by 11.2 (1) and 67.3 (1)°. In the crystal, weak C-H⋯O hydrogen bonds link the molecules related by translation along the b axis into chains.

Original language	English
Pages (from-to)	o3281
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	12
DOIs	https://doi.org/10.1107/S1600536812044443
State	Published - 1 Dec 2012
Externally published	Yes

Keywords

R factor = 0.044
T = 293 K
data-to-parameter ratio = 7.5
mean ω(C-C) = 0.007 Å
single-crystal X-ray study
wR factor = 0.119

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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Cite this

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title = "(2E)-1-Phenyl-2-[1-(2-phenylprop-2-en-1-yl)pyrrolidin-2-ylidene]ethanone",

abstract = "The title compound, C21H21NO, is a vinylogous amide (enaminone) produced by reaction of 1-(2-phenylprop-2-en-1-yl)pyrrolidine-2-thione with phenacyl bromide. In the molecule, the phenyl rings are twisted from the mean plane of the pyrrolidine ring by 11.2 (1) and 67.3 (1)°. In the crystal, weak C-H⋯O hydrogen bonds link the molecules related by translation along the b axis into chains.",

keywords = "R factor = 0.044, T = 293 K, data-to-parameter ratio = 7.5, mean ω(C-C) = 0.007 {\AA}, single-crystal X-ray study, wR factor = 0.119",

author = "Madeley, \{Lee G.\} and Morgans, \{Garreth L.\} and Andreas Lemmerer and Michael, \{Joseph P.\}",

year = "2012",

month = dec,

day = "1",

doi = "10.1107/S1600536812044443",

language = "English",

volume = "68",

pages = "o3281",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - (2E)-1-Phenyl-2-[1-(2-phenylprop-2-en-1-yl)pyrrolidin-2-ylidene]ethanone

AU - Madeley, Lee G.

AU - Morgans, Garreth L.

AU - Lemmerer, Andreas

AU - Michael, Joseph P.

PY - 2012/12/1

Y1 - 2012/12/1

N2 - The title compound, C21H21NO, is a vinylogous amide (enaminone) produced by reaction of 1-(2-phenylprop-2-en-1-yl)pyrrolidine-2-thione with phenacyl bromide. In the molecule, the phenyl rings are twisted from the mean plane of the pyrrolidine ring by 11.2 (1) and 67.3 (1)°. In the crystal, weak C-H⋯O hydrogen bonds link the molecules related by translation along the b axis into chains.

AB - The title compound, C21H21NO, is a vinylogous amide (enaminone) produced by reaction of 1-(2-phenylprop-2-en-1-yl)pyrrolidine-2-thione with phenacyl bromide. In the molecule, the phenyl rings are twisted from the mean plane of the pyrrolidine ring by 11.2 (1) and 67.3 (1)°. In the crystal, weak C-H⋯O hydrogen bonds link the molecules related by translation along the b axis into chains.

KW - R factor = 0.044

KW - T = 293 K

KW - data-to-parameter ratio = 7.5

KW - mean ω(C-C) = 0.007 Å

KW - single-crystal X-ray study

KW - wR factor = 0.119

UR - https://www.scopus.com/pages/publications/84870860092

U2 - 10.1107/S1600536812044443

DO - 10.1107/S1600536812044443

M3 - Article

AN - SCOPUS:84870860092

SN - 1600-5368

VL - 68

SP - o3281

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

(2E)-1-Phenyl-2-[1-(2-phenylprop-2-en-1-yl)pyrrolidin-2-ylidene]ethanone

Abstract

Keywords

ASJC Scopus subject areas

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