3-Bromopyridin-2-amine

Marcelle Johnson; Andreas Lemmerer

doi:10.1107/S1600536811055541

3-Bromopyridin-2-amine

Marcelle Johnson, Andreas Lemmerer

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

In the crystal structure of the title compound, C ₅H ₅BrN ₂, molecules assemble via pairs of N - H⋯N hydrogen bonds into inversion dimers using only the syn H atom on the amine group. These dimers then assemble further into two-dimensional layers via type I C - Br⋯Br [Br⋯Br = 3.693 (s6) Å] halogen bonding along the (102) plane.

Original language	English
Pages (from-to)	o385
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	2
DOIs	https://doi.org/10.1107/S1600536811055541
State	Published - 1 Feb 2012
Externally published	Yes

Keywords

R factor = 0.034
T = 173 K
data-to-parameter ratio = 17.6
mean σ(C-C) = 0.004 Å
single-crystal X-ray study
wR factor = 0.082

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536811055541

Cite this

@article{59626a46901042c8b15cd56aab8ec6d5,

title = "3-Bromopyridin-2-amine",

abstract = "In the crystal structure of the title compound, C 5H 5BrN 2, molecules assemble via pairs of N - H⋯N hydrogen bonds into inversion dimers using only the syn H atom on the amine group. These dimers then assemble further into two-dimensional layers via type I C - Br⋯Br [Br⋯Br = 3.693 (s6) {\AA}] halogen bonding along the (102) plane.",

keywords = "R factor = 0.034, T = 173 K, data-to-parameter ratio = 17.6, mean σ(C-C) = 0.004 {\AA}, single-crystal X-ray study, wR factor = 0.082",

author = "Marcelle Johnson and Andreas Lemmerer",

year = "2012",

month = feb,

day = "1",

doi = "10.1107/S1600536811055541",

language = "English",

volume = "68",

pages = "o385",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - 3-Bromopyridin-2-amine

AU - Johnson, Marcelle

AU - Lemmerer, Andreas

PY - 2012/2/1

Y1 - 2012/2/1

N2 - In the crystal structure of the title compound, C 5H 5BrN 2, molecules assemble via pairs of N - H⋯N hydrogen bonds into inversion dimers using only the syn H atom on the amine group. These dimers then assemble further into two-dimensional layers via type I C - Br⋯Br [Br⋯Br = 3.693 (s6) Å] halogen bonding along the (102) plane.

AB - In the crystal structure of the title compound, C 5H 5BrN 2, molecules assemble via pairs of N - H⋯N hydrogen bonds into inversion dimers using only the syn H atom on the amine group. These dimers then assemble further into two-dimensional layers via type I C - Br⋯Br [Br⋯Br = 3.693 (s6) Å] halogen bonding along the (102) plane.

KW - R factor = 0.034

KW - T = 173 K

KW - data-to-parameter ratio = 17.6

KW - mean σ(C-C) = 0.004 Å

KW - single-crystal X-ray study

KW - wR factor = 0.082

UR - https://www.scopus.com/pages/publications/84863405357

U2 - 10.1107/S1600536811055541

DO - 10.1107/S1600536811055541

M3 - Article

AN - SCOPUS:84863405357

SN - 1600-5368

VL - 68

SP - o385

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

3-Bromopyridin-2-amine

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this