A comparative study of an MCM-41 anchored quaternary ammonium chloride/SnCl4 catalyst and its silica gel analogue

T. M. Jyothi; M. L. Kaliya; M. Herskowitz; M. V. Landau

doi:10.1039/b101843o

A comparative study of an MCM-41 anchored quaternary ammonium chloride/SnCl₄ catalyst and its silica gel analogue

T. M. Jyothi
, M. L. Kaliya
, M. Herskowitz
, M. V. Landau

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

A novel reusable Lewis acid catalyst has been prepared by the heterogenization of a Lewis acid/tetrapropylammonium adduct; anchoring of tin chloride on quaternary ammonium chloride functionalized MCM-41 yielded a catalyst with higher activity compared to the corresponding silica analogue in terms of turnover rates and product yield in the Prins condensation of isobutene and formaldehyde to isoprenol.

Original language	English
Pages (from-to)	992-993
Number of pages	2
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/b101843o
State	Published - 7 Jun 2001

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b101843o

Cite this

@article{066e4b1707aa41e495b8736022a6cdbf,

title = "A comparative study of an MCM-41 anchored quaternary ammonium chloride/SnCl4 catalyst and its silica gel analogue",

abstract = "A novel reusable Lewis acid catalyst has been prepared by the heterogenization of a Lewis acid/tetrapropylammonium adduct; anchoring of tin chloride on quaternary ammonium chloride functionalized MCM-41 yielded a catalyst with higher activity compared to the corresponding silica analogue in terms of turnover rates and product yield in the Prins condensation of isobutene and formaldehyde to isoprenol.",

author = "Jyothi, \{T. M.\} and Kaliya, \{M. L.\} and M. Herskowitz and Landau, \{M. V.\}",

year = "2001",

month = jun,

day = "7",

doi = "10.1039/b101843o",

language = "English",

pages = "992--993",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - A comparative study of an MCM-41 anchored quaternary ammonium chloride/SnCl4 catalyst and its silica gel analogue

AU - Jyothi, T. M.

AU - Kaliya, M. L.

AU - Herskowitz, M.

AU - Landau, M. V.

PY - 2001/6/7

Y1 - 2001/6/7

N2 - A novel reusable Lewis acid catalyst has been prepared by the heterogenization of a Lewis acid/tetrapropylammonium adduct; anchoring of tin chloride on quaternary ammonium chloride functionalized MCM-41 yielded a catalyst with higher activity compared to the corresponding silica analogue in terms of turnover rates and product yield in the Prins condensation of isobutene and formaldehyde to isoprenol.

AB - A novel reusable Lewis acid catalyst has been prepared by the heterogenization of a Lewis acid/tetrapropylammonium adduct; anchoring of tin chloride on quaternary ammonium chloride functionalized MCM-41 yielded a catalyst with higher activity compared to the corresponding silica analogue in terms of turnover rates and product yield in the Prins condensation of isobutene and formaldehyde to isoprenol.

UR - https://www.scopus.com/pages/publications/0035822112

U2 - 10.1039/b101843o

DO - 10.1039/b101843o

M3 - Article

AN - SCOPUS:0035822112

SN - 1359-7345

SP - 992

EP - 993

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

A comparative study of an MCM-41 anchored quaternary ammonium chloride/SnCl₄ catalyst and its silica gel analogue

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this