A curve crossing approach to carbenic reactivity

Addy Pross; Robert A. Moss

doi:10.1016/S0040-4039(00)97674-3

A curve crossing approach to carbenic reactivity

Addy Pross, Robert A. Moss

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Application of the curve crossing model to singlet carbene addition to alkenes reveals that for electrophilic carbenes the reaction barrier is generated from the avoided crossing of DA, ³D^{* 3}A^* and D⁺A^- configurations whereas for nucleophilic carbenes the third configuration is D^-A⁺.

Original language	English
Pages (from-to)	4553-4556
Number of pages	4
Journal	Tetrahedron Letters
Volume	31
Issue number	32
DOIs	https://doi.org/10.1016/S0040-4039(00)97674-3
State	Published - 1 Jan 1990
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)97674-3

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@article{13ced98978d74ff381fd8c03815b284c,

title = "A curve crossing approach to carbenic reactivity",

abstract = "Application of the curve crossing model to singlet carbene addition to alkenes reveals that for electrophilic carbenes the reaction barrier is generated from the avoided crossing of DA, 3D* 3A* and D+A- configurations whereas for nucleophilic carbenes the third configuration is D-A+.",

author = "Addy Pross and Moss, {Robert A.}",

year = "1990",

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doi = "10.1016/S0040-4039(00)97674-3",

language = "English",

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T1 - A curve crossing approach to carbenic reactivity

AU - Pross, Addy

AU - Moss, Robert A.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - Application of the curve crossing model to singlet carbene addition to alkenes reveals that for electrophilic carbenes the reaction barrier is generated from the avoided crossing of DA, 3D* 3A* and D+A- configurations whereas for nucleophilic carbenes the third configuration is D-A+.

AB - Application of the curve crossing model to singlet carbene addition to alkenes reveals that for electrophilic carbenes the reaction barrier is generated from the avoided crossing of DA, 3D* 3A* and D+A- configurations whereas for nucleophilic carbenes the third configuration is D-A+.

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U2 - 10.1016/S0040-4039(00)97674-3

DO - 10.1016/S0040-4039(00)97674-3

M3 - Article

AN - SCOPUS:0025358513

SN - 0040-4039

VL - 31

SP - 4553

EP - 4556

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 32

ER -

A curve crossing approach to carbenic reactivity

Abstract

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