Abstract
Partial reductive hydrolysis of a penta-CoII/III cluster [CoII4(H2O)2(CoIIIW9O34)(PW9O34)]12- (1) leads to the formation of [Co2{Co3(H2O)(Co(OH)2W7O26)(PW9O34)}2]22- (2). This polyoxometalate is made up of two capping [PW9O34]9- units and two bridging [W7O26]10- units that assemble to encapsulate a novel deca-CoII cluster core comprising octahedral and tetrahedral CoII ions.
Original language | English |
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Pages (from-to) | 13245-13248 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 52 |
Issue number | 90 |
DOIs | |
State | Published - 1 Jan 2016 |
Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry