A decacobalt(II) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(II/III) Weakley-type polyoxometalate

Yan Duan; Juan M. Clemente-Juan; José L.G. Fierro; Carlos Giménez-Saiz; Eugenio Coronado

doi:10.1039/c6cc05485d

A decacobalt(II) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(II/III) Weakley-type polyoxometalate

Yan Duan
, Juan M. Clemente-Juan
, José L.G. Fierro
, Carlos Giménez-Saiz
, Eugenio Coronado

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Partial reductive hydrolysis of a penta-Co^II/III cluster [CoII4(H₂O)₂(Co^IIIW₉O₃₄)(PW₉O₃₄)]^12- (1) leads to the formation of [Co₂{Co₃(H₂O)(Co(OH)₂W₇O₂₆)(PW₉O₃₄)}₂]^22- (2). This polyoxometalate is made up of two capping [PW₉O₃₄]^9- units and two bridging [W₇O₂₆]^10- units that assemble to encapsulate a novel deca-Co^II cluster core comprising octahedral and tetrahedral Co^II ions.

Original language	English
Pages (from-to)	13245-13248
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	90
DOIs	https://doi.org/10.1039/c6cc05485d
State	Published - 1 Jan 2016
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "A decacobalt(II) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(II/III) Weakley-type polyoxometalate",

abstract = "Partial reductive hydrolysis of a penta-CoII/III cluster [CoII4(H2O)2(CoIIIW9O34)(PW9O34)]12- (1) leads to the formation of [Co2\{Co3(H2O)(Co(OH)2W7O26)(PW9O34)\}2]22- (2). This polyoxometalate is made up of two capping [PW9O34]9- units and two bridging [W7O26]10- units that assemble to encapsulate a novel deca-CoII cluster core comprising octahedral and tetrahedral CoII ions.",

author = "Yan Duan and Clemente-Juan, \{Juan M.\} and Fierro, \{Jos{\'e} L.G.\} and Carlos Gim{\'e}nez-Saiz and Eugenio Coronado",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

month = jan,

day = "1",

doi = "10.1039/c6cc05485d",

language = "English",

volume = "52",

pages = "13245--13248",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "90",

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TY - JOUR

T1 - A decacobalt(II) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(II/III) Weakley-type polyoxometalate

AU - Duan, Yan

AU - Clemente-Juan, Juan M.

AU - Fierro, José L.G.

AU - Giménez-Saiz, Carlos

AU - Coronado, Eugenio

PY - 2016/1/1

Y1 - 2016/1/1

N2 - Partial reductive hydrolysis of a penta-CoII/III cluster [CoII4(H2O)2(CoIIIW9O34)(PW9O34)]12- (1) leads to the formation of [Co2{Co3(H2O)(Co(OH)2W7O26)(PW9O34)}2]22- (2). This polyoxometalate is made up of two capping [PW9O34]9- units and two bridging [W7O26]10- units that assemble to encapsulate a novel deca-CoII cluster core comprising octahedral and tetrahedral CoII ions.

AB - Partial reductive hydrolysis of a penta-CoII/III cluster [CoII4(H2O)2(CoIIIW9O34)(PW9O34)]12- (1) leads to the formation of [Co2{Co3(H2O)(Co(OH)2W7O26)(PW9O34)}2]22- (2). This polyoxometalate is made up of two capping [PW9O34]9- units and two bridging [W7O26]10- units that assemble to encapsulate a novel deca-CoII cluster core comprising octahedral and tetrahedral CoII ions.

UR - https://www.scopus.com/pages/publications/84994575927

U2 - 10.1039/c6cc05485d

DO - 10.1039/c6cc05485d

M3 - Article

AN - SCOPUS:84994575927

SN - 1359-7345

VL - 52

SP - 13245

EP - 13248

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

A decacobalt(II) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(II/III) Weakley-type polyoxometalate

Abstract

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