A disilanyl dianion and a silyl dianion from a stable silylene

Robert West, Thomas A. Schmedake, Michael Haaf, James Becker, Thomas Mueller

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

The stable silylene, N,N′-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C8K first to a disilanyl dianion and then to a silyl dianion. Both of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane.

Original languageEnglish
Pages (from-to)68-69
Number of pages2
JournalChemistry Letters
Issue number1
DOIs
StatePublished - 1 Jan 2001

ASJC Scopus subject areas

  • General Chemistry

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