A disilanyl dianion and a silyl dianion from a stable silylene

Robert West; Thomas A. Schmedake; Michael Haaf; James Becker; Thomas Mueller

doi:10.1246/cl.2001.68

A disilanyl dianion and a silyl dianion from a stable silylene

Robert West
, Thomas A. Schmedake
, Michael Haaf
, James Becker
, Thomas Mueller

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The stable silylene, N,N′-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C₈K first to a disilanyl dianion and then to a silyl dianion. Both of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane.

Original language	English
Pages (from-to)	68-69
Number of pages	2
Journal	Chemistry Letters
Issue number	1
DOIs	https://doi.org/10.1246/cl.2001.68
State	Published - 1 Jan 2001

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1246/cl.2001.68

Cite this

@article{2844128aef114bfbbd410709643024c1,

title = "A disilanyl dianion and a silyl dianion from a stable silylene",

abstract = "The stable silylene, N,N′-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C8K first to a disilanyl dianion and then to a silyl dianion. Both of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane.",

author = "Robert West and Schmedake, \{Thomas A.\} and Michael Haaf and James Becker and Thomas Mueller",

year = "2001",

month = jan,

day = "1",

doi = "10.1246/cl.2001.68",

language = "English",

pages = "68--69",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "1",

}

TY - JOUR

T1 - A disilanyl dianion and a silyl dianion from a stable silylene

AU - West, Robert

AU - Schmedake, Thomas A.

AU - Haaf, Michael

AU - Becker, James

AU - Mueller, Thomas

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The stable silylene, N,N′-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C8K first to a disilanyl dianion and then to a silyl dianion. Both of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane.

AB - The stable silylene, N,N′-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C8K first to a disilanyl dianion and then to a silyl dianion. Both of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane.

UR - https://www.scopus.com/pages/publications/0035530829

U2 - 10.1246/cl.2001.68

DO - 10.1246/cl.2001.68

M3 - Article

AN - SCOPUS:0035530829

SN - 0366-7022

SP - 68

EP - 69

JO - Chemistry Letters

JF - Chemistry Letters

IS - 1

ER -

A disilanyl dianion and a silyl dianion from a stable silylene

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this