A general approach to N-heterocyclic carbenes with a fused tetracyclic core: Ligands for suzuki-miyaura cross-coupling reaction

Revannath L. Sutar, Vinod Kumar, Rahul D. Shingare, Shridhar Thorat, Rajesh Gonnade, D. Srinivasa Reddy

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The synthesis of an N-heterocyclic carbene (NHC) based on a tetracyclic scaffold by using simple, general, and scalable chemistry is disclosed. The developed route is suitable for introducing multiple substitutions on the tetracyclic scaffold. The utility of the present NHC as a ligand in the Suzuki-Miyaura cross-coupling reaction is demonstrated with a low catalyst loading.

Original languageEnglish
Pages (from-to)4482-4486
Number of pages5
JournalEuropean Journal of Organic Chemistry
Volume2014
Issue number21
DOIs
StatePublished - 1 Jan 2014
Externally publishedYes

Keywords

  • C-C coupling
  • Carbenes
  • Homogeneous catalysis
  • N ligands
  • Synthetic methods

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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