A New Test for the Thermodynamic Consistency of Vapor-Liquid Equilibrium

Jaime Wisniak

doi:10.1021/ie00019a030

A New Test for the Thermodynamic Consistency of Vapor-Liquid Equilibrium

Jaime Wisniak

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

259 Scopus citations

Abstract

A new thermodynamic consistency test of vapor-liquid equilibrium data at low pressure has been proposed based on the equation that describes the bubble point of the mixture. The test can be used in a point-to-point or area manner and requires knowledge or estimation of the heat of vaporization of the pure components. The point-to-point mode is applicable to binary and multicomponent data and simplifies the locating of experimental errors.

Original language	English
Pages (from-to)	1531-1533
Number of pages	3
Journal	Industrial and Engineering Chemistry Research
Volume	32
Issue number	7
DOIs	https://doi.org/10.1021/ie00019a030
State	Published - 1 Jan 1993

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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10.1021/ie00019a030

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title = "A New Test for the Thermodynamic Consistency of Vapor-Liquid Equilibrium",

abstract = "A new thermodynamic consistency test of vapor-liquid equilibrium data at low pressure has been proposed based on the equation that describes the bubble point of the mixture. The test can be used in a point-to-point or area manner and requires knowledge or estimation of the heat of vaporization of the pure components. The point-to-point mode is applicable to binary and multicomponent data and simplifies the locating of experimental errors.",

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AB - A new thermodynamic consistency test of vapor-liquid equilibrium data at low pressure has been proposed based on the equation that describes the bubble point of the mixture. The test can be used in a point-to-point or area manner and requires knowledge or estimation of the heat of vaporization of the pure components. The point-to-point mode is applicable to binary and multicomponent data and simplifies the locating of experimental errors.

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A New Test for the Thermodynamic Consistency of Vapor-Liquid Equilibrium

Abstract

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