A novel formyl complex [(H2O)5CrCHO]2+. A pulse radiolysis study

Haim Cohen, Dan Meyerstein, Alan J. Shusterman, Mathania Weiss

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Abstract

The formyl complex [(H2O)5CrCHO]2+ is formed in aqueous solution via the reaction sequence: Cr2+(aq.) + ·CH(OH)2 → [(H2O)5CrCH(OH) 2]2+ → [(H2O)5CrCHO +2] + H2O, and reduces formaldehyde (k = 1 mol -1 dm3 s-1), yielding CO + CH3OH; the spectra of [(H2O)5CrCH(OH)2]2+ and [(H2O)5CrCHO]2+ are reported.

Original languageEnglish
Pages (from-to)424-425
Number of pages2
JournalChemical Communications
Issue number7
DOIs
StatePublished - 1 Jan 1985

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