A novel synthesis of 3H-pyrroles

S. E. Korostova, S. G. Shevchenko, M. V. Sigalov

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Reaction of isopropylphenyl- and isopropyl-2-thienylketoximes with acetylene, catalyzed by the system MOH (M=Na, K)-DMSO, gave 2-phenyl- and 2-(2-thienyl)-3,3-dimethyl-3H-pyrroles as well as the reaction intermediates O-vinylisopropylphenylketoxime and 2-phenyl-3,3-dimethyl-5-hydroxypyrroline. The yield of the condensation products depends on the structure of the ketoximes and the conditions for the reaction with acetylene.

Original languageEnglish
Pages (from-to)1101-1104
Number of pages4
JournalChemistry of Heterocyclic Compounds
Volume27
Issue number10
DOIs
StatePublished - 1 Oct 1991
Externally publishedYes

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