@article{c0d61c7adba34fafbd1086e942b745df,
title = "A one-dimensional microscopic model for the rate of thermal desorption of an atom. The role of multiphonon processes",
abstract = "A one-dimensional microscopic model is used to calculate the desorption rate and to investigate the role of multiphonon processes in desorption. If the vibrational frequency of the chemisorptive bond is larger than the Debye frequency, multiphonon processes of all orders must be included as in our one-dimensional microscopic multiphonon model.",
author = "Czeslaw Jedrzejek and Freed, {Karl F.} and Shlomo Efrima and Horia Metiu",
note = "Funding Information: * On leave of absence from the Instttute of Statrsttcal Phystcs, Jagelloman Umverstty, Cracow, Poland ** Research supported by hfRL (NSF) facrbttes at the Umversrty of Chicago and NSF Grant CHE77-24652 $ Supported tn part by US-Israel BtnattonaI Sctence Fouttdatton. ** AS. Sloan and CamtlIe and Henry Dreyfus Teacher-Scholar. Supported by NSF CHE 78-16181 and CHE 79-18773. * This choice ts not acctdental. In derlvmg the rate coefticients use IS made of the fact that a hlorse potentral 1s an exponentral functton of the lattice atom posttton. {\textquoteright} Thrs equation 1s less transparent and less stmple than it appears. Its derivatton wtll be dmussed m a future paper.",
year = "1981",
month = apr,
day = "15",
doi = "10.1016/0009-2614(81)80193-5",
language = "English",
volume = "79",
pages = "227--232",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "2",
}