A photo-driven polyoxometalate complex shuttle and its homogeneous catalysis and heterogeneous separation

Yang Yang; Bin Zhang; Yizhan Wang; Liang Yue; Wen Li; Lixin Wu

doi:10.1021/ja4057882

A photo-driven polyoxometalate complex shuttle and its homogeneous catalysis and heterogeneous separation

Yang Yang, Bin Zhang, Yizhan Wang, Liang Yue, Wen Li, Lixin Wu

Research output: Contribution to journal › Article › peer-review

134 Scopus citations

Abstract

A "smart" core-shell complex is designed to combine a catalytic reaction and automatic separation through remote light control. Here, we present the induced amphiphilic behavior of a surfactant-encapsulated polyoxometalate complex with photoresponsive azobenzene units on the periphery. The reversible phase transfer of the complex shuttle between two incompatible phase termini, driven by a photoisomerization-induced polarity change, further facilitates the separation and recycle of the catalyst.

Original language	English
Pages (from-to)	14500-14503
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	39
DOIs	https://doi.org/10.1021/ja4057882
State	Published - 2 Oct 2013
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja4057882

Cite this

@article{cff0918f25394ed49585ab2c13b341e7,

title = "A photo-driven polyoxometalate complex shuttle and its homogeneous catalysis and heterogeneous separation",

abstract = "A {"}smart{"} core-shell complex is designed to combine a catalytic reaction and automatic separation through remote light control. Here, we present the induced amphiphilic behavior of a surfactant-encapsulated polyoxometalate complex with photoresponsive azobenzene units on the periphery. The reversible phase transfer of the complex shuttle between two incompatible phase termini, driven by a photoisomerization-induced polarity change, further facilitates the separation and recycle of the catalyst.",

author = "Yang Yang and Bin Zhang and Yizhan Wang and Liang Yue and Wen Li and Lixin Wu",

year = "2013",

month = oct,

day = "2",

doi = "10.1021/ja4057882",

language = "English",

volume = "135",

pages = "14500--14503",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "39",

}

TY - JOUR

T1 - A photo-driven polyoxometalate complex shuttle and its homogeneous catalysis and heterogeneous separation

AU - Yang, Yang

AU - Zhang, Bin

AU - Wang, Yizhan

AU - Yue, Liang

AU - Li, Wen

AU - Wu, Lixin

PY - 2013/10/2

Y1 - 2013/10/2

N2 - A "smart" core-shell complex is designed to combine a catalytic reaction and automatic separation through remote light control. Here, we present the induced amphiphilic behavior of a surfactant-encapsulated polyoxometalate complex with photoresponsive azobenzene units on the periphery. The reversible phase transfer of the complex shuttle between two incompatible phase termini, driven by a photoisomerization-induced polarity change, further facilitates the separation and recycle of the catalyst.

AB - A "smart" core-shell complex is designed to combine a catalytic reaction and automatic separation through remote light control. Here, we present the induced amphiphilic behavior of a surfactant-encapsulated polyoxometalate complex with photoresponsive azobenzene units on the periphery. The reversible phase transfer of the complex shuttle between two incompatible phase termini, driven by a photoisomerization-induced polarity change, further facilitates the separation and recycle of the catalyst.

UR - http://www.scopus.com/inward/record.url?scp=84885112830&partnerID=8YFLogxK

U2 - 10.1021/ja4057882

DO - 10.1021/ja4057882

M3 - Article

AN - SCOPUS:84885112830

SN - 0002-7863

VL - 135

SP - 14500

EP - 14503

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 39

ER -

A photo-driven polyoxometalate complex shuttle and its homogeneous catalysis and heterogeneous separation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this