A photo-driven polyoxometalate complex shuttle and its homogeneous catalysis and heterogeneous separation

Yang Yang; Bin Zhang; Yizhan Wang; Liang Yue; Wen Li; Lixin Wu

doi:10.1021/ja4057882

A photo-driven polyoxometalate complex shuttle and its homogeneous catalysis and heterogeneous separation

Yang Yang
, Bin Zhang
, Yizhan Wang
, Liang Yue
, Wen Li
, Lixin Wu

Research output: Contribution to journal › Article › peer-review

138 Scopus citations

Abstract

A "smart" core-shell complex is designed to combine a catalytic reaction and automatic separation through remote light control. Here, we present the induced amphiphilic behavior of a surfactant-encapsulated polyoxometalate complex with photoresponsive azobenzene units on the periphery. The reversible phase transfer of the complex shuttle between two incompatible phase termini, driven by a photoisomerization-induced polarity change, further facilitates the separation and recycle of the catalyst.

Original language	English
Pages (from-to)	14500-14503
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	39
DOIs	https://doi.org/10.1021/ja4057882
State	Published - 2 Oct 2013
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Biochemistry
General Chemistry
Colloid and Surface Chemistry

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10.1021/ja4057882

Cite this

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AU - Yang, Yang

AU - Zhang, Bin

AU - Wang, Yizhan

AU - Yue, Liang

AU - Li, Wen

AU - Wu, Lixin

PY - 2013/10/2

Y1 - 2013/10/2

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AB - A "smart" core-shell complex is designed to combine a catalytic reaction and automatic separation through remote light control. Here, we present the induced amphiphilic behavior of a surfactant-encapsulated polyoxometalate complex with photoresponsive azobenzene units on the periphery. The reversible phase transfer of the complex shuttle between two incompatible phase termini, driven by a photoisomerization-induced polarity change, further facilitates the separation and recycle of the catalyst.

UR - https://www.scopus.com/pages/publications/84885112830

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DO - 10.1021/ja4057882

M3 - Article

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A photo-driven polyoxometalate complex shuttle and its homogeneous catalysis and heterogeneous separation

Abstract

ASJC Scopus subject areas

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