A Post-Functionalizable Iso-Polyoxotitanate Cage Cluster

Jie Hou; Junyi Hu; Qing Sun; Guanyun Zhang; Chen Ho Tung; Yifeng Wang

doi:10.1021/acs.inorgchem.6b00982

A Post-Functionalizable Iso-Polyoxotitanate Cage Cluster

Jie Hou
, Junyi Hu
, Qing Sun
, Guanyun Zhang
, Chen Ho Tung
, Yifeng Wang

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

During solvothermal alcoholysis of a mixture of TiI₄ and Ti(OⁱPr)₄, a {I@Ti₂₂} cage cluster encapsulating an OH and iodide guests is crystallized. The {I@Ti₂₂} host-guest cluster surface is postfunctionalizable with catecholate and carboxylate ligands. The synthetic details, structural characterization, spectroscopic properties of the obtained cages clusters are provided. The present study provides candidates for modeling ligand exchange and electron-hole transfer at the titanate nanoparticle surface, and meanwhile offers new opportunities for understanding the TiO₂ nanocrystalline formation in solvothermal processes.

Original language	English
Pages (from-to)	7075-7078
Number of pages	4
Journal	Inorganic Chemistry
Volume	55
Issue number	14
DOIs	https://doi.org/10.1021/acs.inorgchem.6b00982
State	Published - 18 Jul 2016
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/acs.inorgchem.6b00982

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@article{e3f234b680374b7baf5dba7921aa88b3,

title = "A Post-Functionalizable Iso-Polyoxotitanate Cage Cluster",

abstract = "During solvothermal alcoholysis of a mixture of TiI4 and Ti(OiPr)4, a \{I@Ti22\} cage cluster encapsulating an OH and iodide guests is crystallized. The \{I@Ti22\} host-guest cluster surface is postfunctionalizable with catecholate and carboxylate ligands. The synthetic details, structural characterization, spectroscopic properties of the obtained cages clusters are provided. The present study provides candidates for modeling ligand exchange and electron-hole transfer at the titanate nanoparticle surface, and meanwhile offers new opportunities for understanding the TiO2 nanocrystalline formation in solvothermal processes.",

author = "Jie Hou and Junyi Hu and Qing Sun and Guanyun Zhang and Tung, \{Chen Ho\} and Yifeng Wang",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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doi = "10.1021/acs.inorgchem.6b00982",

language = "English",

volume = "55",

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journal = "Inorganic Chemistry",

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TY - JOUR

T1 - A Post-Functionalizable Iso-Polyoxotitanate Cage Cluster

AU - Hou, Jie

AU - Hu, Junyi

AU - Sun, Qing

AU - Zhang, Guanyun

AU - Tung, Chen Ho

AU - Wang, Yifeng

PY - 2016/7/18

Y1 - 2016/7/18

N2 - During solvothermal alcoholysis of a mixture of TiI4 and Ti(OiPr)4, a {I@Ti22} cage cluster encapsulating an OH and iodide guests is crystallized. The {I@Ti22} host-guest cluster surface is postfunctionalizable with catecholate and carboxylate ligands. The synthetic details, structural characterization, spectroscopic properties of the obtained cages clusters are provided. The present study provides candidates for modeling ligand exchange and electron-hole transfer at the titanate nanoparticle surface, and meanwhile offers new opportunities for understanding the TiO2 nanocrystalline formation in solvothermal processes.

AB - During solvothermal alcoholysis of a mixture of TiI4 and Ti(OiPr)4, a {I@Ti22} cage cluster encapsulating an OH and iodide guests is crystallized. The {I@Ti22} host-guest cluster surface is postfunctionalizable with catecholate and carboxylate ligands. The synthetic details, structural characterization, spectroscopic properties of the obtained cages clusters are provided. The present study provides candidates for modeling ligand exchange and electron-hole transfer at the titanate nanoparticle surface, and meanwhile offers new opportunities for understanding the TiO2 nanocrystalline formation in solvothermal processes.

UR - https://www.scopus.com/pages/publications/84978864623

U2 - 10.1021/acs.inorgchem.6b00982

DO - 10.1021/acs.inorgchem.6b00982

M3 - Article

AN - SCOPUS:84978864623

SN - 0020-1669

VL - 55

SP - 7075

EP - 7078

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 14

ER -

A Post-Functionalizable Iso-Polyoxotitanate Cage Cluster

Abstract

ASJC Scopus subject areas

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