A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Claire Besson; Sebastian Schmitz; Kimberly M. Capella; Sivil Kopilevich; Ira A. Weinstock; Paul Kögerler

doi:10.1039/c2dt30502j

A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Claire Besson, Sebastian Schmitz, Kimberly M. Capella, Sivil Kopilevich, Ira A. Weinstock, Paul Kögerler

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid "guests" and azide functions previously attached to binding sites within the cavity of a {Mo ₁₃₂}-type Keplerate reproducibly gives a 2:1 ratio of 1,4- and 1,5-triazoles.

Original language	English
Pages (from-to)	9852-9854
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	33
DOIs	https://doi.org/10.1039/c2dt30502j
State	Published - 7 Sep 2012

ASJC Scopus subject areas

Inorganic Chemistry

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title = "A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor",

abstract = "A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid {"}guests{"} and azide functions previously attached to binding sites within the cavity of a {Mo 132}-type Keplerate reproducibly gives a 2:1 ratio of 1,4- and 1,5-triazoles.",

author = "Claire Besson and Sebastian Schmitz and Capella, {Kimberly M.} and Sivil Kopilevich and Weinstock, {Ira A.} and Paul K{\"o}gerler",

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AU - Weinstock, Ira A.

AU - Kögerler, Paul

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AB - A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid "guests" and azide functions previously attached to binding sites within the cavity of a {Mo 132}-type Keplerate reproducibly gives a 2:1 ratio of 1,4- and 1,5-triazoles.

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JO - Dalton Transactions

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A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Abstract

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