A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Claire Besson, Sebastian Schmitz, Kimberly M. Capella, Sivil Kopilevich, Ira A. Weinstock, Paul Kögerler

Research output: Contribution to journalArticlepeer-review

51 Scopus citations

Abstract

A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid "guests" and azide functions previously attached to binding sites within the cavity of a {Mo 132}-type Keplerate reproducibly gives a 2:1 ratio of 1,4- and 1,5-triazoles.

Original languageEnglish
Pages (from-to)9852-9854
Number of pages3
JournalDalton Transactions
Volume41
Issue number33
DOIs
StatePublished - 7 Sep 2012

ASJC Scopus subject areas

  • Inorganic Chemistry

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