A rigid neutral molecule involving TTF and TCNQ moieties with intrinsic charge- and electron-transfer properties that depend on the polarity of the solvent

Evgeny Tsiperman; James Y. Becker; Vladimir Khodorkovsky; Alex Shames; Lev Shapiro

doi:10.1002/anie.200500812

A rigid neutral molecule involving TTF and TCNQ moieties with intrinsic charge- and electron-transfer properties that depend on the polarity of the solvent

Evgeny Tsiperman, James Y. Becker, Vladimir Khodorkovsky, Alex Shames, Lev Shapiro

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

(Chemical Equation Presented) A one-component acceptor-donor-acceptor compound based on a rigid TCNQ-σ-TTF-σ-TCNQ system (see picture) exhibits a unique case of both intramolecular charge and electron transfer through space that is strongly dependent on the polarity of the medium. The strong dependence of the ground-state electronic structure on the solvent polarity provides an unprecedented case of solvatochromism.

Original language	English
Pages (from-to)	4015-4018
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	26
DOIs	https://doi.org/10.1002/anie.200500812
State	Published - 27 Jun 2005

Keywords

Charge transfer
Donor-acceptor systems
Electron transfer
Solvent effects
Tetrathiafulvalenes

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200500812

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abstract = "(Chemical Equation Presented) A one-component acceptor-donor-acceptor compound based on a rigid TCNQ-σ-TTF-σ-TCNQ system (see picture) exhibits a unique case of both intramolecular charge and electron transfer through space that is strongly dependent on the polarity of the medium. The strong dependence of the ground-state electronic structure on the solvent polarity provides an unprecedented case of solvatochromism.",

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A rigid neutral molecule involving TTF and TCNQ moieties with intrinsic charge- and electron-transfer properties that depend on the polarity of the solvent. / Tsiperman, Evgeny; Becker, James Y.; Khodorkovsky, Vladimir et al.
In: Angewandte Chemie - International Edition, Vol. 44, No. 26, 27.06.2005, p. 4015-4018.

Research output: Contribution to journal › Article › peer-review

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AU - Tsiperman, Evgeny

AU - Becker, James Y.

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AU - Shames, Alex

AU - Shapiro, Lev

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KW - Donor-acceptor systems

KW - Electron transfer

KW - Solvent effects

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A rigid neutral molecule involving TTF and TCNQ moieties with intrinsic charge- and electron-transfer properties that depend on the polarity of the solvent

Abstract

Keywords

ASJC Scopus subject areas

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