A Study on the Mechanism of the Thermal Decomposition of Ammonium Perchlorate

A. Burcat; B. Carmon; I. Pelly; M. Steinberg

doi:10.1002/ijch.196800109

A Study on the Mechanism of the Thermal Decomposition of Ammonium Perchlorate

A. Burcat, B. Carmon, I. Pelly, M. Steinberg

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Abstract

The thermal decomposition of ammonium perchlorate in the presence of potassium chloride and chromium (III) oxide was investigated using K³⁶ Cl and⁵¹ Cr₂ O₃ to elucidate the reaction mechanism. Two simultaneous routes are suggested for the decomposition. It was found that double decomposition in vacuo between potassium chloride and ammonium perchlorate does not result in the formation of potassium perchlorate. Chromium (III) oxide was not oxidized by ammonium perchlorate, but oxidation to the hexavalent state took place when potassium chloride was present.

Original language	English
Pages (from-to)	859-864
Number of pages	6
Journal	Israel Journal of Chemistry
Volume	6
Issue number	6
DOIs	https://doi.org/10.1002/ijch.196800109
State	Published - 1 Jan 1968
Externally published	Yes

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Chemistry (all)

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10.1002/ijch.196800109

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title = "A Study on the Mechanism of the Thermal Decomposition of Ammonium Perchlorate",

abstract = "The thermal decomposition of ammonium perchlorate in the presence of potassium chloride and chromium (III) oxide was investigated using K36 Cl and51 Cr2 O3 to elucidate the reaction mechanism. Two simultaneous routes are suggested for the decomposition. It was found that double decomposition in vacuo between potassium chloride and ammonium perchlorate does not result in the formation of potassium perchlorate. Chromium (III) oxide was not oxidized by ammonium perchlorate, but oxidation to the hexavalent state took place when potassium chloride was present.",

author = "A. Burcat and B. Carmon and I. Pelly and M. Steinberg",

year = "1968",

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doi = "10.1002/ijch.196800109",

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AU - Burcat, A.

AU - Carmon, B.

AU - Pelly, I.

AU - Steinberg, M.

PY - 1968/1/1

Y1 - 1968/1/1

N2 - The thermal decomposition of ammonium perchlorate in the presence of potassium chloride and chromium (III) oxide was investigated using K36 Cl and51 Cr2 O3 to elucidate the reaction mechanism. Two simultaneous routes are suggested for the decomposition. It was found that double decomposition in vacuo between potassium chloride and ammonium perchlorate does not result in the formation of potassium perchlorate. Chromium (III) oxide was not oxidized by ammonium perchlorate, but oxidation to the hexavalent state took place when potassium chloride was present.

AB - The thermal decomposition of ammonium perchlorate in the presence of potassium chloride and chromium (III) oxide was investigated using K36 Cl and51 Cr2 O3 to elucidate the reaction mechanism. Two simultaneous routes are suggested for the decomposition. It was found that double decomposition in vacuo between potassium chloride and ammonium perchlorate does not result in the formation of potassium perchlorate. Chromium (III) oxide was not oxidized by ammonium perchlorate, but oxidation to the hexavalent state took place when potassium chloride was present.

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DO - 10.1002/ijch.196800109

M3 - Article

AN - SCOPUS:84989994887

VL - 6

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JO - Israel Journal of Chemistry

JF - Israel Journal of Chemistry

SN - 0021-2148

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ER -

A Study on the Mechanism of the Thermal Decomposition of Ammonium Perchlorate

Abstract

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