Absorption spectra of NO3- in solution

Dan Meyerstein; Avner Treinin

doi:10.1039/TF9615702104

Absorption spectra of NO₃^- in solution

Dan Meyerstein, Avner Treinin

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

The nature of the electronic transitions, responsible for the absorption bands of NO₃^- in solution, is discussed. Environmental effects were studied to ascertain the type of transition responsible for the high intensity band. The effects detected on this band are entirely different from that displayed by electron-transfer band and hence it is assigned to internal transition, which is probably π→π. The effects studied are due to change of temperature, solvent and addition of various substances, mainly electrolytes. Ionic effects are discussed in view of the various types of ionic association. It is suggested that H-bonding plays a prominent role in the mechanism of these effects.

Original language	English
Pages (from-to)	2104-2112
Number of pages	9
Journal	Transactions of the Faraday Society
Volume	57
DOIs	https://doi.org/10.1039/TF9615702104
State	Published - 1 Dec 1961
Externally published	Yes

ASJC Scopus subject areas

General Engineering
General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The nature of the electronic transitions, responsible for the absorption bands of NO3- in solution, is discussed. Environmental effects were studied to ascertain the type of transition responsible for the high intensity band. The effects detected on this band are entirely different from that displayed by electron-transfer band and hence it is assigned to internal transition, which is probably π→π. The effects studied are due to change of temperature, solvent and addition of various substances, mainly electrolytes. Ionic effects are discussed in view of the various types of ionic association. It is suggested that H-bonding plays a prominent role in the mechanism of these effects.",

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AB - The nature of the electronic transitions, responsible for the absorption bands of NO3- in solution, is discussed. Environmental effects were studied to ascertain the type of transition responsible for the high intensity band. The effects detected on this band are entirely different from that displayed by electron-transfer band and hence it is assigned to internal transition, which is probably π→π. The effects studied are due to change of temperature, solvent and addition of various substances, mainly electrolytes. Ionic effects are discussed in view of the various types of ionic association. It is suggested that H-bonding plays a prominent role in the mechanism of these effects.

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Absorption spectra of NO₃^- in solution

Abstract

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