Absorption spectra of NO3- in solution

Dan Meyerstein, Avner Treinin

Research output: Contribution to journalArticlepeer-review

56 Scopus citations

Abstract

The nature of the electronic transitions, responsible for the absorption bands of NO3- in solution, is discussed. Environmental effects were studied to ascertain the type of transition responsible for the high intensity band. The effects detected on this band are entirely different from that displayed by electron-transfer band and hence it is assigned to internal transition, which is probably π→π. The effects studied are due to change of temperature, solvent and addition of various substances, mainly electrolytes. Ionic effects are discussed in view of the various types of ionic association. It is suggested that H-bonding plays a prominent role in the mechanism of these effects.

Original languageEnglish
Pages (from-to)2104-2112
Number of pages9
JournalTransactions of the Faraday Society
Volume57
DOIs
StatePublished - 1 Dec 1961
Externally publishedYes

ASJC Scopus subject areas

  • Engineering (all)
  • Physics and Astronomy (all)
  • Physical and Theoretical Chemistry

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