Adsorption effects in aluminophosphate molecular sieves studied by27Al double-rotation NMR

R. Jelinek; B. F. Chmelka; Y. Wu; M. E. Davis; J. G. Unlan; R. Gronsky; A. Pines

doi:10.1007/BF00770899

Adsorption effects in aluminophosphate molecular sieves studied by²⁷Al double-rotation NMR

R. Jelinek, B. F. Chmelka, Y. Wu, M. E. Davis, J. G. Unlan, R. Gronsky, A. Pines

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

²⁷Al double rotation NMR (DOR) spectroscopy is used to investigate structural changes in the framework of several aluminophosphate molecular sieves upon adsorption of water. The shapes, widths, and positions of the spectral lines yield information on the aluminum environments, adsorption sites, and degree of structural disorder undergone upon water adsorption.

Original language	English
Pages (from-to)	65-73
Number of pages	9
Journal	Catalysis Letters
Volume	15
Issue number	1-2
DOIs	https://doi.org/10.1007/BF00770899
State	Published - 1 Mar 1992
Externally published	Yes

Keywords

NMR (DOR) spectroscopy
adsorption sites
aluminophosphate
aluminum environment
molecular sieves
structural disorder
water adsorption

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1007/BF00770899

Cite this

@article{7b11c244ef8b420db897dbd9aaff38b8,

title = "Adsorption effects in aluminophosphate molecular sieves studied by27Al double-rotation NMR",

abstract = "27Al double rotation NMR (DOR) spectroscopy is used to investigate structural changes in the framework of several aluminophosphate molecular sieves upon adsorption of water. The shapes, widths, and positions of the spectral lines yield information on the aluminum environments, adsorption sites, and degree of structural disorder undergone upon water adsorption.",

keywords = "NMR (DOR) spectroscopy, adsorption sites, aluminophosphate, aluminum environment, molecular sieves, structural disorder, water adsorption",

author = "R. Jelinek and Chmelka, \{B. F.\} and Y. Wu and Davis, \{M. E.\} and Unlan, \{J. G.\} and R. Gronsky and A. Pines",

year = "1992",

month = mar,

day = "1",

doi = "10.1007/BF00770899",

language = "English",

volume = "15",

pages = "65--73",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "1-2",

}

TY - JOUR

T1 - Adsorption effects in aluminophosphate molecular sieves studied by27Al double-rotation NMR

AU - Jelinek, R.

AU - Chmelka, B. F.

AU - Wu, Y.

AU - Davis, M. E.

AU - Unlan, J. G.

AU - Gronsky, R.

AU - Pines, A.

PY - 1992/3/1

Y1 - 1992/3/1

N2 - 27Al double rotation NMR (DOR) spectroscopy is used to investigate structural changes in the framework of several aluminophosphate molecular sieves upon adsorption of water. The shapes, widths, and positions of the spectral lines yield information on the aluminum environments, adsorption sites, and degree of structural disorder undergone upon water adsorption.

AB - 27Al double rotation NMR (DOR) spectroscopy is used to investigate structural changes in the framework of several aluminophosphate molecular sieves upon adsorption of water. The shapes, widths, and positions of the spectral lines yield information on the aluminum environments, adsorption sites, and degree of structural disorder undergone upon water adsorption.

KW - NMR (DOR) spectroscopy

KW - adsorption sites

KW - aluminophosphate

KW - aluminum environment

KW - molecular sieves

KW - structural disorder

KW - water adsorption

UR - https://www.scopus.com/pages/publications/0009799814

U2 - 10.1007/BF00770899

DO - 10.1007/BF00770899

M3 - Article

AN - SCOPUS:0009799814

SN - 1011-372X

VL - 15

SP - 65

EP - 73

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -