Advanced sol–gel process for efficient heterogeneous ring-closing metathesis

Shiran Aharon, Dan Meyerstein, Eyal Tzur, Dror Shamir, Yael Albo, Ariela Burg

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Olefin metathesis, a powerful synthetic method with numerous practical applications, can be improved by developing heterogeneous catalysts that can be recycled. In this study, a single-stage process for the entrapment of ruthenium-based catalysts was developed by the sol–gel process. System effectiveness was quantified by measuring the conversion of the ring-closing metathesis reaction of the substrate diethyl diallylmalonate and the leakage of the catalysts from the matrix. The results indicate that the nature of the precursor affects pore size and catalyst activity. Moreover, matrices prepared with tetraethoxysilane at an alkaline pH exhibit a better reaction rate than in the homogenous system under certain reaction conditions. To the best of our knowledge, this is the first study to present a one-step process that is simpler and faster than the methods reported in the literature for catalyst entrapment by the sol–gel process under standard conditions.

Original languageEnglish
Article number12506
JournalScientific Reports
Volume11
Issue number1
DOIs
StatePublished - 1 Dec 2021

ASJC Scopus subject areas

  • General

Fingerprint

Dive into the research topics of 'Advanced sol–gel process for efficient heterogeneous ring-closing metathesis'. Together they form a unique fingerprint.

Cite this