Alkenylation by 5-hexen-2-one oxime: Prototropic isomerization under trofimov reaction conditions

A. M. Vasil'tsov; A. I. Mikhaleva; R. N. Nesterenko; M. V. Sigalov

doi:10.1007/BF00766996

Alkenylation by 5-hexen-2-one oxime: Prototropic isomerization under trofimov reaction conditions

A. M. Vasil'tsov, A. I. Mikhaleva, R. N. Nesterenko, M. V. Sigalov

Research output: Contribution to journal › Article › peer-review

Abstract

From 5-hexene-2-one oxime (I) and acetylene in KOH/DMSO, 2-methyl-3-(2-propenyl)pyrrole (II), E- and Z-2-methyl-3-(1-propenyl)pyrroles (III), and E- and Z-1-vinyl-2-methyl-3-(1-propenyl)pyrroles (V) were synthesized. The isomerization of the alkenyl radical of pyrroles II was studied.

Original language	English
Pages (from-to)	400-402
Number of pages	3
Journal	Chemistry of Heterocyclic Compounds
Volume	28
Issue number	4
DOIs	https://doi.org/10.1007/BF00766996
State	Published - 1 Apr 1992
Externally published	Yes

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Organic Chemistry

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title = "Alkenylation by 5-hexen-2-one oxime: Prototropic isomerization under trofimov reaction conditions",

abstract = "From 5-hexene-2-one oxime (I) and acetylene in KOH/DMSO, 2-methyl-3-(2-propenyl)pyrrole (II), E- and Z-2-methyl-3-(1-propenyl)pyrroles (III), and E- and Z-1-vinyl-2-methyl-3-(1-propenyl)pyrroles (V) were synthesized. The isomerization of the alkenyl radical of pyrroles II was studied.",

author = "Vasil'tsov, {A. M.} and Mikhaleva, {A. I.} and Nesterenko, {R. N.} and Sigalov, {M. V.}",

year = "1992",

month = apr,

day = "1",

doi = "10.1007/BF00766996",

language = "English",

volume = "28",

pages = "400--402",

journal = "Chemistry of Heterocyclic Compounds",

issn = "0009-3122",

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TY - JOUR

T1 - Alkenylation by 5-hexen-2-one oxime

T2 - Prototropic isomerization under trofimov reaction conditions

AU - Vasil'tsov, A. M.

AU - Mikhaleva, A. I.

AU - Nesterenko, R. N.

AU - Sigalov, M. V.

PY - 1992/4/1

Y1 - 1992/4/1

N2 - From 5-hexene-2-one oxime (I) and acetylene in KOH/DMSO, 2-methyl-3-(2-propenyl)pyrrole (II), E- and Z-2-methyl-3-(1-propenyl)pyrroles (III), and E- and Z-1-vinyl-2-methyl-3-(1-propenyl)pyrroles (V) were synthesized. The isomerization of the alkenyl radical of pyrroles II was studied.

AB - From 5-hexene-2-one oxime (I) and acetylene in KOH/DMSO, 2-methyl-3-(2-propenyl)pyrrole (II), E- and Z-2-methyl-3-(1-propenyl)pyrroles (III), and E- and Z-1-vinyl-2-methyl-3-(1-propenyl)pyrroles (V) were synthesized. The isomerization of the alkenyl radical of pyrroles II was studied.

UR - http://www.scopus.com/inward/record.url?scp=34249830856&partnerID=8YFLogxK

U2 - 10.1007/BF00766996

DO - 10.1007/BF00766996

M3 - Article

AN - SCOPUS:34249830856

SN - 0009-3122

VL - 28

SP - 400

EP - 402

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

IS - 4

ER -

Alkenylation by 5-hexen-2-one oxime: Prototropic isomerization under trofimov reaction conditions

Abstract

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