An ABC stacking supramolecular discotic columnar structure constructed via hydrogen-bonded hexamers

Shi Jin; Yuguo Ma; Steven C. Zimmerman; Stephen Z.D. Cheng

doi:10.1021/cm0498988

An ABC stacking supramolecular discotic columnar structure constructed via hydrogen-bonded hexamers

Shi Jin, Yuguo Ma, Steven C. Zimmerman, Stephen Z.D. Cheng

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

An ABC intracolumn stacking scheme was discovered in a discotic columnar liquid-crystalline phase, which formed by self-assembly of hexameric supramolecular disks. Strong DDA-AAD hydrogen bonding dictated the formation of hexameric disks. Molecular structural simulation suggested that interplay among secondary interactions (π-π, electrostatic, and steric) between the hexameric disks determined the formation of this columnar phase.

Original language	English
Pages (from-to)	2975-2977
Number of pages	3
Journal	Chemistry of Materials
Volume	16
Issue number	16
DOIs	https://doi.org/10.1021/cm0498988
State	Published - 10 Aug 2004
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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10.1021/cm0498988

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title = "An ABC stacking supramolecular discotic columnar structure constructed via hydrogen-bonded hexamers",

abstract = "An ABC intracolumn stacking scheme was discovered in a discotic columnar liquid-crystalline phase, which formed by self-assembly of hexameric supramolecular disks. Strong DDA-AAD hydrogen bonding dictated the formation of hexameric disks. Molecular structural simulation suggested that interplay among secondary interactions (π-π, electrostatic, and steric) between the hexameric disks determined the formation of this columnar phase.",

author = "Shi Jin and Yuguo Ma and Zimmerman, {Steven C.} and Cheng, {Stephen Z.D.}",

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AU - Jin, Shi

AU - Ma, Yuguo

AU - Zimmerman, Steven C.

AU - Cheng, Stephen Z.D.

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Y1 - 2004/8/10

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AB - An ABC intracolumn stacking scheme was discovered in a discotic columnar liquid-crystalline phase, which formed by self-assembly of hexameric supramolecular disks. Strong DDA-AAD hydrogen bonding dictated the formation of hexameric disks. Molecular structural simulation suggested that interplay among secondary interactions (π-π, electrostatic, and steric) between the hexameric disks determined the formation of this columnar phase.

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An ABC stacking supramolecular discotic columnar structure constructed via hydrogen-bonded hexamers

Abstract

ASJC Scopus subject areas

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