An All Solid-State Zinc−Air Battery with a Corrosion-Resistant Air Electrode

Mruthyunjayachari Chattanahalli Devendrachari; Chidananda Basappa; Ravikumar Thimmappa; Zahid Manzoor Bhat; Harish Makri Nimbegondi Kotresh; Alagar Raja Kottaichamy; Swapnil Varhade; Siddhi Khaire; Kallam Ramareddy Venugopala Reddy; Musthafa Ottakam Thotiyl

doi:10.1002/celc.201800269

An All Solid-State Zinc−Air Battery with a Corrosion-Resistant Air Electrode

Mruthyunjayachari Chattanahalli Devendrachari
, Chidananda Basappa
, Ravikumar Thimmappa
, Zahid Manzoor Bhat
, Harish Makri Nimbegondi Kotresh
, Alagar Raja Kottaichamy
, Swapnil Varhade
, Siddhi Khaire
, Kallam Ramareddy Venugopala Reddy
, Musthafa Ottakam Thotiyl

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

We illustrate an all solid-state Zn−air battery by utilizing the ability of a titanium-nitride-functionalized molecular catalyst to mediate the oxygen reduction reaction by avoiding the parasitic corrosion chemistry and the hydroxide-holding capacity of the Zirfon membrane. The efficient ionic communication between the half-cell electrodes provided by the Zirfon membrane in combination with the chemical/electrochemical stability of the TiN-based air electrode ultimately led to an all solid-state and air-breathing battery possessing high durability and stability.

Original language	English
Pages (from-to)	1817-1821
Number of pages	5
Journal	ChemElectroChem
Volume	5
Issue number	14
DOIs	https://doi.org/10.1002/celc.201800269
State	Published - 11 Jul 2018
Externally published	Yes

Keywords

corrosion resistance
molecular catalysts
titanium nitride
zinc−air batteries

ASJC Scopus subject areas

Catalysis
Electrochemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/celc.201800269

Cite this

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title = "An All Solid-State Zinc−Air Battery with a Corrosion-Resistant Air Electrode",

abstract = "We illustrate an all solid-state Zn−air battery by utilizing the ability of a titanium-nitride-functionalized molecular catalyst to mediate the oxygen reduction reaction by avoiding the parasitic corrosion chemistry and the hydroxide-holding capacity of the Zirfon membrane. The efficient ionic communication between the half-cell electrodes provided by the Zirfon membrane in combination with the chemical/electrochemical stability of the TiN-based air electrode ultimately led to an all solid-state and air-breathing battery possessing high durability and stability.",

keywords = "corrosion resistance, molecular catalysts, titanium nitride, zinc−air batteries",

author = "Devendrachari, \{Mruthyunjayachari Chattanahalli\} and Chidananda Basappa and Ravikumar Thimmappa and Bhat, \{Zahid Manzoor\} and Kotresh, \{Harish Makri Nimbegondi\} and Kottaichamy, \{Alagar Raja\} and Swapnil Varhade and Siddhi Khaire and Reddy, \{Kallam Ramareddy Venugopala\} and Thotiyl, \{Musthafa Ottakam\}",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = jul,

day = "11",

doi = "10.1002/celc.201800269",

language = "English",

volume = "5",

pages = "1817--1821",

journal = "ChemElectroChem",

issn = "2196-0216",

publisher = "John Wiley and Sons Ltd",

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}

TY - JOUR

T1 - An All Solid-State Zinc−Air Battery with a Corrosion-Resistant Air Electrode

AU - Devendrachari, Mruthyunjayachari Chattanahalli

AU - Basappa, Chidananda

AU - Thimmappa, Ravikumar

AU - Bhat, Zahid Manzoor

AU - Kotresh, Harish Makri Nimbegondi

AU - Kottaichamy, Alagar Raja

AU - Varhade, Swapnil

AU - Khaire, Siddhi

AU - Reddy, Kallam Ramareddy Venugopala

AU - Thotiyl, Musthafa Ottakam

PY - 2018/7/11

Y1 - 2018/7/11

N2 - We illustrate an all solid-state Zn−air battery by utilizing the ability of a titanium-nitride-functionalized molecular catalyst to mediate the oxygen reduction reaction by avoiding the parasitic corrosion chemistry and the hydroxide-holding capacity of the Zirfon membrane. The efficient ionic communication between the half-cell electrodes provided by the Zirfon membrane in combination with the chemical/electrochemical stability of the TiN-based air electrode ultimately led to an all solid-state and air-breathing battery possessing high durability and stability.

AB - We illustrate an all solid-state Zn−air battery by utilizing the ability of a titanium-nitride-functionalized molecular catalyst to mediate the oxygen reduction reaction by avoiding the parasitic corrosion chemistry and the hydroxide-holding capacity of the Zirfon membrane. The efficient ionic communication between the half-cell electrodes provided by the Zirfon membrane in combination with the chemical/electrochemical stability of the TiN-based air electrode ultimately led to an all solid-state and air-breathing battery possessing high durability and stability.

KW - corrosion resistance

KW - molecular catalysts

KW - titanium nitride

KW - zinc−air batteries

UR - https://www.scopus.com/pages/publications/85049804373

U2 - 10.1002/celc.201800269

DO - 10.1002/celc.201800269

M3 - Article

AN - SCOPUS:85049804373

SN - 2196-0216

VL - 5

SP - 1817

EP - 1821

JO - ChemElectroChem

JF - ChemElectroChem

IS - 14

ER -

An All Solid-State Zinc−Air Battery with a Corrosion-Resistant Air Electrode

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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