(matrix presented) Quantum mechanical calculations show that N,N cycloaddition of alkenes and alkynes to s-tetrazines is possible as an alternative to the well-known C,C cycloaddition (Carboni-Lindsey reaction). Formation of 1,2,4-triazole derivatives (formal product of N,N cycloaddition) along with the pyrazole (formal product of C,C cycloaddition) corroborates this theoretical prediction.
|Number of pages||3|
|State||Published - 31 May 2001|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry