An intermediate with a copper-carbon bond formed by the reaction of copper ions with ·CH2CO2H radicals in aqueous solutions

Mira Freiberg; Dan Meyerstein

doi:10.1039/C39770000127

An intermediate with a copper-carbon bond formed by the reaction of copper ions with ·CH₂CO₂H radicals in aqueous solutions

Mira Freiberg
, Dan Meyerstein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The radical ·CH₂CO₂^- reacts with Cu²⁺ (aq) forming an unstable intermediate with a specific rate of (6·4 ± 1·5) × 10⁸ 1 mol^-1 s^-1; the intermediate, Cu-CH₂CO₂⁺, decomposes via a first-order process with k 2·8 ± 0·3 s^-1.

Original language	English
Pages (from-to)	127-128
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39770000127
State	Published - 1 Dec 1977

ASJC Scopus subject areas

Molecular Medicine

Access to Document

10.1039/C39770000127

Cite this

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title = "An intermediate with a copper-carbon bond formed by the reaction of copper ions with ·CH2CO2H radicals in aqueous solutions",

abstract = "The radical ·CH2CO2- reacts with Cu2+ (aq) forming an unstable intermediate with a specific rate of (6·4 ± 1·5) × 108 1 mol-1 s-1; the intermediate, Cu-CH2CO2+, decomposes via a first-order process with k 2·8 ± 0·3 s-1.",

author = "Mira Freiberg and Dan Meyerstein",

year = "1977",

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doi = "10.1039/C39770000127",

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journal = "Journal of the Chemical Society D: Chemical Communications",

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T1 - An intermediate with a copper-carbon bond formed by the reaction of copper ions with ·CH2CO2H radicals in aqueous solutions

AU - Freiberg, Mira

AU - Meyerstein, Dan

PY - 1977/12/1

Y1 - 1977/12/1

N2 - The radical ·CH2CO2- reacts with Cu2+ (aq) forming an unstable intermediate with a specific rate of (6·4 ± 1·5) × 108 1 mol-1 s-1; the intermediate, Cu-CH2CO2+, decomposes via a first-order process with k 2·8 ± 0·3 s-1.

AB - The radical ·CH2CO2- reacts with Cu2+ (aq) forming an unstable intermediate with a specific rate of (6·4 ± 1·5) × 108 1 mol-1 s-1; the intermediate, Cu-CH2CO2+, decomposes via a first-order process with k 2·8 ± 0·3 s-1.

UR - https://www.scopus.com/pages/publications/37049102323

U2 - 10.1039/C39770000127

DO - 10.1039/C39770000127

M3 - Article

AN - SCOPUS:37049102323

SN - 0022-4936

SP - 127

EP - 128

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 4