Analysis of electronically nonadiabatic chemical reactions: An information theoretic approach

U. Dinur; R. Kosloff; R. D. Levine; M. J. Berry

doi:10.1016/0009-2614(75)85255-9

Analysis of electronically nonadiabatic chemical reactions: An information theoretic approach

U. Dinur, R. Kosloff, R. D. Levine, M. J. Berry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

A practical procedure for the determination of branching ratios for reactions which lead to either excited or electronically ground state products is outlined. The method is applied to four reactions which could (on energetic grounds) produce an electronically excited iodine atom. No case of a complete inversion is found, but one reaction (F + HI) is predicted to yield a statistical, (one half), I^*(²P_1/2) to I(²P_3/2) ratio.

Original language	English
Pages (from-to)	199-205
Number of pages	7
Journal	Chemical Physics Letters
Volume	34
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(75)85255-9
State	Published - 15 Jul 1975
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Analysis of electronically nonadiabatic chemical reactions: An information theoretic approach",

abstract = "A practical procedure for the determination of branching ratios for reactions which lead to either excited or electronically ground state products is outlined. The method is applied to four reactions which could (on energetic grounds) produce an electronically excited iodine atom. No case of a complete inversion is found, but one reaction (F + HI) is predicted to yield a statistical, (one half), I*(2P1/2) to I(2P3/2) ratio.",

author = "U. Dinur and R. Kosloff and Levine, {R. D.} and Berry, {M. J.}",

note = "Funding Information: * Work supported by the Stitung Volkswagenwerk and by the tiectorate of CbemicaI Scienms, U.S. .4ir Force Offi= of ScienGc Research undei Grant AFOSR-73-2423. {\textquoteright} Camille 2~5 P_ enry tieyfus FoundntiorqTeacher-Scholar, AEked P. Slave Foundation Research Fellow.",

year = "1975",

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day = "15",

doi = "10.1016/0009-2614(75)85255-9",

language = "English",

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pages = "199--205",

journal = "Chemical Physics Letters",

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number = "2",

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TY - JOUR

T1 - Analysis of electronically nonadiabatic chemical reactions

T2 - An information theoretic approach

AU - Dinur, U.

AU - Kosloff, R.

AU - Levine, R. D.

AU - Berry, M. J.

N1 - Funding Information: * Work supported by the Stitung Volkswagenwerk and by the tiectorate of CbemicaI Scienms, U.S. .4ir Force Offi= of ScienGc Research undei Grant AFOSR-73-2423. ’ Camille 2~5 P_ enry tieyfus FoundntiorqTeacher-Scholar, AEked P. Slave Foundation Research Fellow.

PY - 1975/7/15

Y1 - 1975/7/15

N2 - A practical procedure for the determination of branching ratios for reactions which lead to either excited or electronically ground state products is outlined. The method is applied to four reactions which could (on energetic grounds) produce an electronically excited iodine atom. No case of a complete inversion is found, but one reaction (F + HI) is predicted to yield a statistical, (one half), I*(2P1/2) to I(2P3/2) ratio.

AB - A practical procedure for the determination of branching ratios for reactions which lead to either excited or electronically ground state products is outlined. The method is applied to four reactions which could (on energetic grounds) produce an electronically excited iodine atom. No case of a complete inversion is found, but one reaction (F + HI) is predicted to yield a statistical, (one half), I*(2P1/2) to I(2P3/2) ratio.

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U2 - 10.1016/0009-2614(75)85255-9

DO - 10.1016/0009-2614(75)85255-9

M3 - Article

AN - SCOPUS:0000905745

SN - 0009-2614

VL - 34

SP - 199

EP - 205

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Analysis of electronically nonadiabatic chemical reactions: An information theoretic approach

Abstract

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