Analysis of the Bio-oil Produced by the Hydrothermal Liquefaction of Biomass Using High-Resolution Mass Spectrometry and Isotope Exchange

Yury Kostyukevich; Sergey Osipenko; Kirill Rindin; Alexander Zherebker; Oxana Kovaleva; Lidiia Rumiantseva; Ludmila Borisova; Nataliya Borisova; Mikhail S. Vlaskin; Eugene Nikolaev

doi:10.1021/acs.energyfuels.1c01649

Analysis of the Bio-oil Produced by the Hydrothermal Liquefaction of Biomass Using High-Resolution Mass Spectrometry and Isotope Exchange

Yury Kostyukevich, Sergey Osipenko, Kirill Rindin, Alexander Zherebker, Oxana Kovaleva, Lidiia Rumiantseva, Ludmila Borisova, Nataliya Borisova, Mikhail S. Vlaskin, Eugene Nikolaev

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Production of bio-oil by hydrothermal liquefaction of biomass is a promising way to achieve several sustainable development goals: renewable energy, proper waste treatment, reduction of greenhouse gas emissions, etc. For the wide application of bio-oil in industry and transport, it is important to study its molecular composition. However, the molecular composition of bio-oil is almost as complicated as that of natural petroleum, and despite the considerable amount of research, it is not fully understood. Here, we applied high-resolution mass spectrometry, collision induced dissociation, the isotope (H/D and 16O/18O) exchange approach, and other analytical techniques in order to obtain chemical information about individual molecules of bio-oil. We proved the presence of different nitrogen functionalities including quaternary nitrogen in the bio-oil. Analyzing MS/MS spectra of individual compounds, we proposed possible structures of individual molecules of bio-oil.

Original language	English
Pages (from-to)	12208-12215
Number of pages	8
Journal	Energy and Fuels
Volume	35
Issue number	15
DOIs	https://doi.org/10.1021/acs.energyfuels.1c01649
State	Published - 5 Aug 2021
Externally published	Yes

ASJC Scopus subject areas

General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acs.energyfuels.1c01649

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Kostyukevich, Y., Osipenko, S., Rindin, K., Zherebker, A., Kovaleva, O., Rumiantseva, L., Borisova, L., Borisova, N., Vlaskin, M. S., & Nikolaev, E. (2021). Analysis of the Bio-oil Produced by the Hydrothermal Liquefaction of Biomass Using High-Resolution Mass Spectrometry and Isotope Exchange. Energy and Fuels, 35(15), 12208-12215. https://doi.org/10.1021/acs.energyfuels.1c01649

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title = "Analysis of the Bio-oil Produced by the Hydrothermal Liquefaction of Biomass Using High-Resolution Mass Spectrometry and Isotope Exchange",

abstract = "Production of bio-oil by hydrothermal liquefaction of biomass is a promising way to achieve several sustainable development goals: renewable energy, proper waste treatment, reduction of greenhouse gas emissions, etc. For the wide application of bio-oil in industry and transport, it is important to study its molecular composition. However, the molecular composition of bio-oil is almost as complicated as that of natural petroleum, and despite the considerable amount of research, it is not fully understood. Here, we applied high-resolution mass spectrometry, collision induced dissociation, the isotope (H/D and 16O/18O) exchange approach, and other analytical techniques in order to obtain chemical information about individual molecules of bio-oil. We proved the presence of different nitrogen functionalities including quaternary nitrogen in the bio-oil. Analyzing MS/MS spectra of individual compounds, we proposed possible structures of individual molecules of bio-oil.",

author = "Yury Kostyukevich and Sergey Osipenko and Kirill Rindin and Alexander Zherebker and Oxana Kovaleva and Lidiia Rumiantseva and Ludmila Borisova and Nataliya Borisova and Vlaskin, {Mikhail S.} and Eugene Nikolaev",

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Kostyukevich, Y, Osipenko, S, Rindin, K, Zherebker, A, Kovaleva, O, Rumiantseva, L, Borisova, L, Borisova, N, Vlaskin, MS & Nikolaev, E 2021, 'Analysis of the Bio-oil Produced by the Hydrothermal Liquefaction of Biomass Using High-Resolution Mass Spectrometry and Isotope Exchange', Energy and Fuels, vol. 35, no. 15, pp. 12208-12215. https://doi.org/10.1021/acs.energyfuels.1c01649

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AU - Kostyukevich, Yury

AU - Osipenko, Sergey

AU - Rindin, Kirill

AU - Zherebker, Alexander

AU - Kovaleva, Oxana

AU - Rumiantseva, Lidiia

AU - Borisova, Ludmila

AU - Borisova, Nataliya

AU - Vlaskin, Mikhail S.

AU - Nikolaev, Eugene

PY - 2021/8/5

Y1 - 2021/8/5

N2 - Production of bio-oil by hydrothermal liquefaction of biomass is a promising way to achieve several sustainable development goals: renewable energy, proper waste treatment, reduction of greenhouse gas emissions, etc. For the wide application of bio-oil in industry and transport, it is important to study its molecular composition. However, the molecular composition of bio-oil is almost as complicated as that of natural petroleum, and despite the considerable amount of research, it is not fully understood. Here, we applied high-resolution mass spectrometry, collision induced dissociation, the isotope (H/D and 16O/18O) exchange approach, and other analytical techniques in order to obtain chemical information about individual molecules of bio-oil. We proved the presence of different nitrogen functionalities including quaternary nitrogen in the bio-oil. Analyzing MS/MS spectra of individual compounds, we proposed possible structures of individual molecules of bio-oil.

AB - Production of bio-oil by hydrothermal liquefaction of biomass is a promising way to achieve several sustainable development goals: renewable energy, proper waste treatment, reduction of greenhouse gas emissions, etc. For the wide application of bio-oil in industry and transport, it is important to study its molecular composition. However, the molecular composition of bio-oil is almost as complicated as that of natural petroleum, and despite the considerable amount of research, it is not fully understood. Here, we applied high-resolution mass spectrometry, collision induced dissociation, the isotope (H/D and 16O/18O) exchange approach, and other analytical techniques in order to obtain chemical information about individual molecules of bio-oil. We proved the presence of different nitrogen functionalities including quaternary nitrogen in the bio-oil. Analyzing MS/MS spectra of individual compounds, we proposed possible structures of individual molecules of bio-oil.

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Analysis of the Bio-oil Produced by the Hydrothermal Liquefaction of Biomass Using High-Resolution Mass Spectrometry and Isotope Exchange

Abstract

ASJC Scopus subject areas

UN SDGs

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