Analytical procedure for simultaneous use of seven fluorobenzoates in multitracer tests

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    17 Scopus citations

    Abstract

    An analytical procedure allowing simultaneous use of seven fluorobenzoate (FBA) isomers was developed and examined through column and field tracer experiments. The analytical method, based on high performance liquid chromatography (HPLC), included a reverse-phase separation method. This method was found to be very efficient for the FBA analysis, allowing accurate determination of seven FBAs in a single HPLC run, while avoiding analytical interference of other natural water constituents or pollutants. Consequently, this separation method allows the simultaneous use of seven isomers in multitracer tests in highly saline or contaminated environments. The mobility properties of the FBAs were examined in percolation experiments through a column filled with a mixture of crushed chalk and common fracture filling and coating material. The FBAs behaved conservatively as compared to bromid. All seven FBA isomers were successfully used in a multitracer test in a field percolation experiment designed to identify flowpath along a fracture plane.

    Original languageEnglish
    Pages (from-to)366-370
    Number of pages5
    JournalGround Water
    Volume39
    Issue number3
    DOIs
    StatePublished - 1 Jan 2001

    ASJC Scopus subject areas

    • Water Science and Technology
    • Computers in Earth Sciences

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