Anodic oxidation of aroyl and phenacyl azides

Anand Dhiman; James Y. Becker

doi:10.1016/j.jelechem.2007.03.009

Anodic oxidation of aroyl and phenacyl azides

Anand Dhiman, James Y. Becker

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The electrochemical oxidation of two types of organic azides, XC₆H₄COCH₂N₃ and XC₆H₄CON₃ (X = H, p-CH₃, p-OCH₃, p-Br) derivatives has been investigated, both by cyclic voltammetry and preparative electrolysis. The effects of substitution, electrolysis technique, solvent and anodes on the outcome of the electrochemical oxidation are discussed. In general, various products were obtained mostly due to CO-CH₂N₃ and CO-N₃ bonds cleavage.

Original language	English
Pages (from-to)	133-136
Number of pages	4
Journal	Journal of Electroanalytical Chemistry
Volume	604
Issue number	2
DOIs	https://doi.org/10.1016/j.jelechem.2007.03.009
State	Published - 15 Jun 2007

Keywords

Aroyl azides
Cyclic voltammetry
Electrochemical oxidation
Phenacyl azides

ASJC Scopus subject areas

Analytical Chemistry
General Chemical Engineering
Electrochemistry

Access to Document

10.1016/j.jelechem.2007.03.009

Cite this

@article{72d38246231640b287ff9e2174e8243c,

title = "Anodic oxidation of aroyl and phenacyl azides",

abstract = "The electrochemical oxidation of two types of organic azides, XC6H4COCH2N3 and XC6H4CON3 (X = H, p-CH3, p-OCH3, p-Br) derivatives has been investigated, both by cyclic voltammetry and preparative electrolysis. The effects of substitution, electrolysis technique, solvent and anodes on the outcome of the electrochemical oxidation are discussed. In general, various products were obtained mostly due to CO-CH2N3 and CO-N3 bonds cleavage.",

keywords = "Aroyl azides, Cyclic voltammetry, Electrochemical oxidation, Phenacyl azides",

author = "Anand Dhiman and Becker, {James Y.}",

note = "Funding Information: The authors are grateful to “VATAT” (through the Israel Council for Higher Education) for granting a post-doctoral fellowship to Dr. A. Dhiman.",

year = "2007",

month = jun,

day = "15",

doi = "10.1016/j.jelechem.2007.03.009",

language = "English",

volume = "604",

pages = "133--136",

journal = "Journal of Electroanalytical Chemistry",

issn = "1572-6657",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Anodic oxidation of aroyl and phenacyl azides

AU - Dhiman, Anand

AU - Becker, James Y.

N1 - Funding Information: The authors are grateful to “VATAT” (through the Israel Council for Higher Education) for granting a post-doctoral fellowship to Dr. A. Dhiman.

PY - 2007/6/15

Y1 - 2007/6/15

N2 - The electrochemical oxidation of two types of organic azides, XC6H4COCH2N3 and XC6H4CON3 (X = H, p-CH3, p-OCH3, p-Br) derivatives has been investigated, both by cyclic voltammetry and preparative electrolysis. The effects of substitution, electrolysis technique, solvent and anodes on the outcome of the electrochemical oxidation are discussed. In general, various products were obtained mostly due to CO-CH2N3 and CO-N3 bonds cleavage.

AB - The electrochemical oxidation of two types of organic azides, XC6H4COCH2N3 and XC6H4CON3 (X = H, p-CH3, p-OCH3, p-Br) derivatives has been investigated, both by cyclic voltammetry and preparative electrolysis. The effects of substitution, electrolysis technique, solvent and anodes on the outcome of the electrochemical oxidation are discussed. In general, various products were obtained mostly due to CO-CH2N3 and CO-N3 bonds cleavage.

KW - Aroyl azides

KW - Cyclic voltammetry

KW - Electrochemical oxidation

KW - Phenacyl azides

UR - http://www.scopus.com/inward/record.url?scp=34248581752&partnerID=8YFLogxK

U2 - 10.1016/j.jelechem.2007.03.009

DO - 10.1016/j.jelechem.2007.03.009

M3 - Article

AN - SCOPUS:34248581752

SN - 1572-6657

VL - 604

SP - 133

EP - 136

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 2

ER -

Anodic oxidation of aroyl and phenacyl azides

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this