Anti-phase domain boundaries in ZnGeP2 (ZGP)

Y. Shimony, R. Fledman, I. Dahan, G. Kimmel

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Coherently oriented cubic defects were recently reported to exist within the tetragonal lattice of zinc-germanium-phosphide, ZnGeP2 (ZGP). X-ray diffraction utilizing whole pattern optimization (Rietveld method) and line-profile-fitting (LPF) enabled us to identify these defects. In the present research, transmission electron microscopy (TEM) was used for direct observation of these defects. The bright field and dark field TEM images of the ZGP foil indicate the existence of anti-phase domain boundaries (APB). Electron diffraction patterns clearly reveal two coherently oriented entities, one of a tetragonal symmetry in accordance with the chalcopyrite lattice, the other however of a cubic symmetry. This confirms our former finding of the existence of coherently oriented cubic defects in as-grown chalcopyrite ZGP crystal.

Original languageEnglish
Pages (from-to)119-123
Number of pages5
JournalOptical Materials
Volume16
Issue number1-2
DOIs
StatePublished - 1 Jan 2001
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • General Computer Science
  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Electrical and Electronic Engineering

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