Antiferromagnetic complexes with metal-metal bonds.: Part XXX. Synthesis and molecular structures of the antiferromagnetic adducts [Cp′Cr(μ-SPh)]2(μ3-Se)·ML (Cp′=η5-CH3C5H4, ML=Fe3(μ3-S)2(CO)8, Mn2(CO)9, Mn2(CO)8), paramagnetic complexes Cp′Cr(μ-SPh)3Mn(CO)3 and [Cp′Cr(μ-SPh)]2Te, diamagnetic cluster Cp′2Cr2(μ-SPh)(μ3-S)(μ3-Te)Co(CO)2

A. A. Pasynskii; I. V. Skabitski; Yu V. Torubaev; N. I. Semenova; V. M. Novotortsev; O. G. Ellert; K. A. Lyssenko

doi:10.1016/S0022-328X(03)00048-2

Antiferromagnetic complexes with metal-metal bonds. Part XXX. Synthesis and molecular structures of the antiferromagnetic adducts [Cp′Cr(μ-SPh)]₂(μ₃-Se)·ML (Cp′=η⁵-CH₃C₅H_4, ML=Fe₃(μ₃-S)₂(CO)₈, Mn₂(CO)₉, Mn₂(CO)₈), paramagnetic complexes Cp′Cr(μ-SPh)₃Mn(CO)₃ and [Cp′Cr(μ-SPh)]₂Te, diamagnetic cluster Cp′₂Cr₂(μ-SPh)(μ₃-S)(μ₃-Te)Co(CO)₂

A. A. Pasynskii, I. V. Skabitski, Yu V. Torubaev, N. I. Semenova, V. M. Novotortsev, O. G. Ellert, K. A. Lyssenko

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The photochemical reactions of antiferromagnetic heterochalcogenic complex [Cp′Cr(μ-SPh)]₂(μ-Se) (1) (Cp′=η⁵-CH₃C₅H₄) with Fe₃(μ₃-Se)₂(CO)₉ or Mn₂(CO)₁₀ at room temperature gives new mixed-metal heterochalcogenic clusters [Cp′Cr(μ-SPh)]₂(μ₃-Se)Fe₃(μ₃-Se)₂(CO)₈ (2), [Cp′Cr(μ-SPh)]₂(μ₃-Se)Mn₂(CO)₉ (3) and [Cp′Cr(μ-SPh)]₂(μ₄-Se)Mn₂(CO)₈ (4) which are antiferromagnetic (-2J=256, 230 and 324 cm^-1, respectively) and characterized by X-ray diffraction analysis (2: Cr-Cr 2.763(1) Å; Fe-Fe 2.6184(9) and 2.706(1) Å; Cr-Se 2.447, 2.460 Å; 3: Cr-Cr 2.762 Å; Mn-Mn 2.920 Å; Cr-Se 2.447, 2.460 Å; 4: Cr-Cr 2.816 Å, Mn-Mn 2.835 Å, Cr-Se 2.464 Å). The photochemical reaction of 1 and Mn₂(CO)₁₀ at higher temperature gives the paramagnetic complex Cp′Cr(μ-SPh)₃Mn(CO)₃ (5) with a weak Cr-Mn bond (3.0239 Å). The new heterochalcogenic complex [Cp′Cr(μ-SPh)]₂(μ-Te) (6) which obtained at the interaction of [Cp′Cr(CO)(μ-SPh)]₂ with Te and was studied by X-ray method (Cr-Cr 2.772 Å, Cr-S 2.359 Å, Cr-Te 2.601-2.607 Å, Cr-Te-Cr 64.3°), reacted with Co₂(CO)₈ with formation of the diamagnetic mixed-metal heterochalcogenic cluster [Cp′₂Cr₂(SPh)](μ₃-S)(μ₃-Te)Co(CO)₂ (7) (Cr-Cr 2. 646 Å, Cr-Co 2.627 Å-2.623 Å, Cr-μ₃-S 2.282-2.299 Å, Co-μ₃-S 2.199 Å, Cr-μ₃-Te 2.630-2.618 Å, Co-μ₃-Te 2.466 Å, Cr-μ-S_Ph 2.335 Å). The role of super-exchange spin-spin interaction through the chalcogen bridge atom is discussed.

Original language	English
Pages (from-to)	91-100
Number of pages	10
Journal	Journal of Organometallic Chemistry
Volume	671
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(03)00048-2
State	Published - 1 Apr 2003
Externally published	Yes

Keywords

Chalcogenide
Chromium
Cobalt
Cyclopentadienyl complexes
Iron
Magnetic properties
Manganese
Metal carbonyls
Mixed-metal clusters
X-ray analyses

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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Pasynskii, A. A., Skabitski, I. V., Torubaev, Y. V., Semenova, N. I., Novotortsev, V. M., Ellert, O. G., & Lyssenko, K. A. (2003). Antiferromagnetic complexes with metal-metal bonds. Part XXX. Synthesis and molecular structures of the antiferromagnetic adducts [Cp′Cr(μ-SPh)]₂(μ₃-Se)·ML (Cp′=η⁵-CH₃C₅H_4, ML=Fe₃(μ₃-S)₂(CO)₈, Mn₂(CO)₉, Mn₂(CO)₈), paramagnetic complexes Cp′Cr(μ-SPh)₃Mn(CO)₃ and [Cp′Cr(μ-SPh)]₂Te, diamagnetic cluster Cp′₂Cr₂(μ-SPh)(μ₃-S)(μ₃-Te)Co(CO)₂. Journal of Organometallic Chemistry, 671(1-2), 91-100. https://doi.org/10.1016/S0022-328X(03)00048-2

Pasynskii, A. A. ; Skabitski, I. V. ; Torubaev, Yu V. et al. / Antiferromagnetic complexes with metal-metal bonds. Part XXX. Synthesis and molecular structures of the antiferromagnetic adducts [Cp′Cr(μ-SPh)]₂(μ₃-Se)·ML (Cp′=η⁵-CH₃C₅H_4, ML=Fe₃(μ₃-S)₂(CO)₈, Mn₂(CO)₉, Mn₂(CO)₈), paramagnetic complexes Cp′Cr(μ-SPh)₃Mn(CO)₃ and [Cp′Cr(μ-SPh)]₂Te, diamagnetic cluster Cp′₂Cr₂(μ-SPh)(μ₃-S)(μ₃-Te)Co(CO)₂. In: Journal of Organometallic Chemistry. 2003 ; Vol. 671, No. 1-2. pp. 91-100.

@article{826069da54e840cdb3309a4846e172e5,

title = "Antiferromagnetic complexes with metal-metal bonds.: Part XXX. Synthesis and molecular structures of the antiferromagnetic adducts [Cp′Cr(μ-SPh)]2(μ3-Se)·ML (Cp′=η5-CH3C5H4, ML=Fe3(μ3-S)2(CO)8, Mn2(CO)9, Mn2(CO)8), paramagnetic complexes Cp′Cr(μ-SPh)3Mn(CO)3 and [Cp′Cr(μ-SPh)]2Te, diamagnetic cluster Cp′2Cr2(μ-SPh)(μ3-S)(μ3-Te)Co(CO)2",

abstract = "The photochemical reactions of antiferromagnetic heterochalcogenic complex [Cp′Cr(μ-SPh)]2(μ-Se) (1) (Cp′=η5-CH3C5H4) with Fe3(μ3-Se)2(CO)9 or Mn2(CO)10 at room temperature gives new mixed-metal heterochalcogenic clusters [Cp′Cr(μ-SPh)]2(μ3-Se)Fe3(μ3-Se)2(CO)8 (2), [Cp′Cr(μ-SPh)]2(μ3-Se)Mn2(CO)9 (3) and [Cp′Cr(μ-SPh)]2(μ4-Se)Mn2(CO)8 (4) which are antiferromagnetic (-2J=256, 230 and 324 cm-1, respectively) and characterized by X-ray diffraction analysis (2: Cr-Cr 2.763(1) {\AA}; Fe-Fe 2.6184(9) and 2.706(1) {\AA}; Cr-Se 2.447, 2.460 {\AA}; 3: Cr-Cr 2.762 {\AA}; Mn-Mn 2.920 {\AA}; Cr-Se 2.447, 2.460 {\AA}; 4: Cr-Cr 2.816 {\AA}, Mn-Mn 2.835 {\AA}, Cr-Se 2.464 {\AA}). The photochemical reaction of 1 and Mn2(CO)10 at higher temperature gives the paramagnetic complex Cp′Cr(μ-SPh)3Mn(CO)3 (5) with a weak Cr-Mn bond (3.0239 {\AA}). The new heterochalcogenic complex [Cp′Cr(μ-SPh)]2(μ-Te) (6) which obtained at the interaction of [Cp′Cr(CO)(μ-SPh)]2 with Te and was studied by X-ray method (Cr-Cr 2.772 {\AA}, Cr-S 2.359 {\AA}, Cr-Te 2.601-2.607 {\AA}, Cr-Te-Cr 64.3°), reacted with Co2(CO)8 with formation of the diamagnetic mixed-metal heterochalcogenic cluster [Cp′2Cr2(SPh)](μ3-S)(μ3-Te)Co(CO)2 (7) (Cr-Cr 2. 646 {\AA}, Cr-Co 2.627 {\AA}-2.623 {\AA}, Cr-μ3-S 2.282-2.299 {\AA}, Co-μ3-S 2.199 {\AA}, Cr-μ3-Te 2.630-2.618 {\AA}, Co-μ3-Te 2.466 {\AA}, Cr-μ-SPh 2.335 {\AA}). The role of super-exchange spin-spin interaction through the chalcogen bridge atom is discussed.",

keywords = "Chalcogenide, Chromium, Cobalt, Cyclopentadienyl complexes, Iron, Magnetic properties, Manganese, Metal carbonyls, Mixed-metal clusters, X-ray analyses",

author = "Pasynskii, {A. A.} and Skabitski, {I. V.} and Torubaev, {Yu V.} and Semenova, {N. I.} and Novotortsev, {V. M.} and Ellert, {O. G.} and Lyssenko, {K. A.}",

year = "2003",

month = apr,

day = "1",

doi = "10.1016/S0022-328X(03)00048-2",

language = "English",

volume = "671",

pages = "91--100",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

}

Pasynskii, AA, Skabitski, IV, Torubaev, YV, Semenova, NI, Novotortsev, VM, Ellert, OG & Lyssenko, KA 2003, 'Antiferromagnetic complexes with metal-metal bonds. Part XXX. Synthesis and molecular structures of the antiferromagnetic adducts [Cp′Cr(μ-SPh)]₂(μ₃-Se)·ML (Cp′=η⁵-CH₃C₅H_4, ML=Fe₃(μ₃-S)₂(CO)₈, Mn₂(CO)₉, Mn₂(CO)₈), paramagnetic complexes Cp′Cr(μ-SPh)₃Mn(CO)₃ and [Cp′Cr(μ-SPh)]₂Te, diamagnetic cluster Cp′₂Cr₂(μ-SPh)(μ₃-S)(μ₃-Te)Co(CO)₂', Journal of Organometallic Chemistry, vol. 671, no. 1-2, pp. 91-100. https://doi.org/10.1016/S0022-328X(03)00048-2

Antiferromagnetic complexes with metal-metal bonds. Part XXX. Synthesis and molecular structures of the antiferromagnetic adducts [Cp′Cr(μ-SPh)]₂(μ₃-Se)·ML (Cp′=η⁵-CH₃C₅H_4, ML=Fe₃(μ₃-S)₂(CO)₈, Mn₂(CO)₉, Mn₂(CO)₈), paramagnetic complexes Cp′Cr(μ-SPh)₃Mn(CO)₃ and [Cp′Cr(μ-SPh)]₂Te, diamagnetic cluster Cp′₂Cr₂(μ-SPh)(μ₃-S)(μ₃-Te)Co(CO)₂. / Pasynskii, A. A.; Skabitski, I. V.; Torubaev, Yu V. et al.
In: Journal of Organometallic Chemistry, Vol. 671, No. 1-2, 01.04.2003, p. 91-100.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Antiferromagnetic complexes with metal-metal bonds.

T2 - Part XXX. Synthesis and molecular structures of the antiferromagnetic adducts [Cp′Cr(μ-SPh)]2(μ3-Se)·ML (Cp′=η5-CH3C5H4, ML=Fe3(μ3-S)2(CO)8, Mn2(CO)9, Mn2(CO)8), paramagnetic complexes Cp′Cr(μ-SPh)3Mn(CO)3 and [Cp′Cr(μ-SPh)]2Te, diamagnetic cluster Cp′2Cr2(μ-SPh)(μ3-S)(μ3-Te)Co(CO)2

AU - Pasynskii, A. A.

AU - Skabitski, I. V.

AU - Torubaev, Yu V.

AU - Semenova, N. I.

AU - Novotortsev, V. M.

AU - Ellert, O. G.

AU - Lyssenko, K. A.

PY - 2003/4/1

Y1 - 2003/4/1

N2 - The photochemical reactions of antiferromagnetic heterochalcogenic complex [Cp′Cr(μ-SPh)]2(μ-Se) (1) (Cp′=η5-CH3C5H4) with Fe3(μ3-Se)2(CO)9 or Mn2(CO)10 at room temperature gives new mixed-metal heterochalcogenic clusters [Cp′Cr(μ-SPh)]2(μ3-Se)Fe3(μ3-Se)2(CO)8 (2), [Cp′Cr(μ-SPh)]2(μ3-Se)Mn2(CO)9 (3) and [Cp′Cr(μ-SPh)]2(μ4-Se)Mn2(CO)8 (4) which are antiferromagnetic (-2J=256, 230 and 324 cm-1, respectively) and characterized by X-ray diffraction analysis (2: Cr-Cr 2.763(1) Å; Fe-Fe 2.6184(9) and 2.706(1) Å; Cr-Se 2.447, 2.460 Å; 3: Cr-Cr 2.762 Å; Mn-Mn 2.920 Å; Cr-Se 2.447, 2.460 Å; 4: Cr-Cr 2.816 Å, Mn-Mn 2.835 Å, Cr-Se 2.464 Å). The photochemical reaction of 1 and Mn2(CO)10 at higher temperature gives the paramagnetic complex Cp′Cr(μ-SPh)3Mn(CO)3 (5) with a weak Cr-Mn bond (3.0239 Å). The new heterochalcogenic complex [Cp′Cr(μ-SPh)]2(μ-Te) (6) which obtained at the interaction of [Cp′Cr(CO)(μ-SPh)]2 with Te and was studied by X-ray method (Cr-Cr 2.772 Å, Cr-S 2.359 Å, Cr-Te 2.601-2.607 Å, Cr-Te-Cr 64.3°), reacted with Co2(CO)8 with formation of the diamagnetic mixed-metal heterochalcogenic cluster [Cp′2Cr2(SPh)](μ3-S)(μ3-Te)Co(CO)2 (7) (Cr-Cr 2. 646 Å, Cr-Co 2.627 Å-2.623 Å, Cr-μ3-S 2.282-2.299 Å, Co-μ3-S 2.199 Å, Cr-μ3-Te 2.630-2.618 Å, Co-μ3-Te 2.466 Å, Cr-μ-SPh 2.335 Å). The role of super-exchange spin-spin interaction through the chalcogen bridge atom is discussed.

AB - The photochemical reactions of antiferromagnetic heterochalcogenic complex [Cp′Cr(μ-SPh)]2(μ-Se) (1) (Cp′=η5-CH3C5H4) with Fe3(μ3-Se)2(CO)9 or Mn2(CO)10 at room temperature gives new mixed-metal heterochalcogenic clusters [Cp′Cr(μ-SPh)]2(μ3-Se)Fe3(μ3-Se)2(CO)8 (2), [Cp′Cr(μ-SPh)]2(μ3-Se)Mn2(CO)9 (3) and [Cp′Cr(μ-SPh)]2(μ4-Se)Mn2(CO)8 (4) which are antiferromagnetic (-2J=256, 230 and 324 cm-1, respectively) and characterized by X-ray diffraction analysis (2: Cr-Cr 2.763(1) Å; Fe-Fe 2.6184(9) and 2.706(1) Å; Cr-Se 2.447, 2.460 Å; 3: Cr-Cr 2.762 Å; Mn-Mn 2.920 Å; Cr-Se 2.447, 2.460 Å; 4: Cr-Cr 2.816 Å, Mn-Mn 2.835 Å, Cr-Se 2.464 Å). The photochemical reaction of 1 and Mn2(CO)10 at higher temperature gives the paramagnetic complex Cp′Cr(μ-SPh)3Mn(CO)3 (5) with a weak Cr-Mn bond (3.0239 Å). The new heterochalcogenic complex [Cp′Cr(μ-SPh)]2(μ-Te) (6) which obtained at the interaction of [Cp′Cr(CO)(μ-SPh)]2 with Te and was studied by X-ray method (Cr-Cr 2.772 Å, Cr-S 2.359 Å, Cr-Te 2.601-2.607 Å, Cr-Te-Cr 64.3°), reacted with Co2(CO)8 with formation of the diamagnetic mixed-metal heterochalcogenic cluster [Cp′2Cr2(SPh)](μ3-S)(μ3-Te)Co(CO)2 (7) (Cr-Cr 2. 646 Å, Cr-Co 2.627 Å-2.623 Å, Cr-μ3-S 2.282-2.299 Å, Co-μ3-S 2.199 Å, Cr-μ3-Te 2.630-2.618 Å, Co-μ3-Te 2.466 Å, Cr-μ-SPh 2.335 Å). The role of super-exchange spin-spin interaction through the chalcogen bridge atom is discussed.

KW - Chalcogenide

KW - Chromium

KW - Cobalt

KW - Cyclopentadienyl complexes

KW - Iron

KW - Magnetic properties

KW - Manganese

KW - Metal carbonyls

KW - Mixed-metal clusters

KW - X-ray analyses

UR - http://www.scopus.com/inward/record.url?scp=0037389183&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(03)00048-2

DO - 10.1016/S0022-328X(03)00048-2

M3 - Article

AN - SCOPUS:0037389183

SN - 0022-328X

VL - 671

SP - 91

EP - 100

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -