Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe3)]2(μ4-S)[PtMe3(μ-I)]2

A. A. Pasynskii; Y. V. Torubaev; S. E. Nefedov; I. L. Eremenko; O. G. Ellert; V. K. Belsky; A. I. Stastch

doi:10.1016/S0022-328X(96)06738-1

Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe₃)]₂(μ₄-S)[PtMe₃(μ-I)]₂

A. A. Pasynskii, Y. V. Torubaev, S. E. Nefedov, I. L. Eremenko, O. G. Ellert, V. K. Belsky, A. I. Stastch

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The reaction of [CpCr(μ-SCMe₃)]₂(μ-S) (1) with [PtMe₃I]₄ in hot benzene leads to the formation of the tetranuclear cluster I[CpCr(μ-SCMe₃)]₂(μ₄-S)[PtMe₃(μ-I)]₂ (2). According to X-ray data, cluster 2 contains a molecule of 1 (Cr-Cr 2.761(9) Å, Cr-S-Cr 70.1(4)°), coordinated to a diplatinum fragment via a μ₄-S atom (Pt-S 2.583(10) and 2.560(9) Å). 2 has antiferromagnetic properties (-2J = 202cm^-1) due to the interaction between two paramagnetic Cr(III) centers (S = 3/2).

Original language	English
Pages (from-to)	433-436
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	536-537
DOIs	https://doi.org/10.1016/S0022-328X(96)06738-1
State	Published - 30 May 1997
Externally published	Yes

Keywords

Antiferromagnetic behaviour
Chromium
Crystal structure
Platinum
Sulfido

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(96)06738-1

Cite this

Pasynskii, A. A., Torubaev, Y. V., Nefedov, S. E., Eremenko, I. L., Ellert, O. G., Belsky, V. K., & Stastch, A. I. (1997). Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe₃)]₂(μ₄-S)[PtMe₃(μ-I)]₂. Journal of Organometallic Chemistry, 536-537, 433-436. https://doi.org/10.1016/S0022-328X(96)06738-1

@article{2e9d6d5fd9d64570a8f91fcd20801cb4,

title = "Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe3)]2(μ4-S)[PtMe3(μ-I)]2",

abstract = "The reaction of [CpCr(μ-SCMe3)]2(μ-S) (1) with [PtMe3I]4 in hot benzene leads to the formation of the tetranuclear cluster I[CpCr(μ-SCMe3)]2(μ4-S)[PtMe3(μ-I)]2 (2). According to X-ray data, cluster 2 contains a molecule of 1 (Cr-Cr 2.761(9) {\AA}, Cr-S-Cr 70.1(4)°), coordinated to a diplatinum fragment via a μ4-S atom (Pt-S 2.583(10) and 2.560(9) {\AA}). 2 has antiferromagnetic properties (-2J = 202cm-1) due to the interaction between two paramagnetic Cr(III) centers (S = 3/2).",

keywords = "Antiferromagnetic behaviour, Chromium, Crystal structure, Platinum, Sulfido",

author = "Pasynskii, {A. A.} and Torubaev, {Y. V.} and Nefedov, {S. E.} and Eremenko, {I. L.} and Ellert, {O. G.} and Belsky, {V. K.} and Stastch, {A. I.}",

note = "Funding Information: The authors are grateful to the Russian Foundation of Fundamental Research for financial support (Grants 96-03-33171 and 96-03-33172).",

year = "1997",

month = may,

day = "30",

doi = "10.1016/S0022-328X(96)06738-1",

language = "English",

volume = "536-537",

pages = "433--436",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

Pasynskii, AA, Torubaev, YV, Nefedov, SE, Eremenko, IL, Ellert, OG, Belsky, VK & Stastch, AI 1997, 'Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe₃)]₂(μ₄-S)[PtMe₃(μ-I)]₂', Journal of Organometallic Chemistry, vol. 536-537, pp. 433-436. https://doi.org/10.1016/S0022-328X(96)06738-1

Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe₃)]₂(μ₄-S)[PtMe₃(μ-I)]₂. / Pasynskii, A. A.; Torubaev, Y. V.; Nefedov, S. E. et al.
In: Journal of Organometallic Chemistry, Vol. 536-537, 30.05.1997, p. 433-436.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe3)]2(μ4-S)[PtMe3(μ-I)]2

AU - Pasynskii, A. A.

AU - Torubaev, Y. V.

AU - Nefedov, S. E.

AU - Eremenko, I. L.

AU - Ellert, O. G.

AU - Belsky, V. K.

AU - Stastch, A. I.

N1 - Funding Information: The authors are grateful to the Russian Foundation of Fundamental Research for financial support (Grants 96-03-33171 and 96-03-33172).

PY - 1997/5/30

Y1 - 1997/5/30

N2 - The reaction of [CpCr(μ-SCMe3)]2(μ-S) (1) with [PtMe3I]4 in hot benzene leads to the formation of the tetranuclear cluster I[CpCr(μ-SCMe3)]2(μ4-S)[PtMe3(μ-I)]2 (2). According to X-ray data, cluster 2 contains a molecule of 1 (Cr-Cr 2.761(9) Å, Cr-S-Cr 70.1(4)°), coordinated to a diplatinum fragment via a μ4-S atom (Pt-S 2.583(10) and 2.560(9) Å). 2 has antiferromagnetic properties (-2J = 202cm-1) due to the interaction between two paramagnetic Cr(III) centers (S = 3/2).

AB - The reaction of [CpCr(μ-SCMe3)]2(μ-S) (1) with [PtMe3I]4 in hot benzene leads to the formation of the tetranuclear cluster I[CpCr(μ-SCMe3)]2(μ4-S)[PtMe3(μ-I)]2 (2). According to X-ray data, cluster 2 contains a molecule of 1 (Cr-Cr 2.761(9) Å, Cr-S-Cr 70.1(4)°), coordinated to a diplatinum fragment via a μ4-S atom (Pt-S 2.583(10) and 2.560(9) Å). 2 has antiferromagnetic properties (-2J = 202cm-1) due to the interaction between two paramagnetic Cr(III) centers (S = 3/2).

KW - Antiferromagnetic behaviour

KW - Chromium

KW - Crystal structure

KW - Platinum

KW - Sulfido

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U2 - 10.1016/S0022-328X(96)06738-1

DO - 10.1016/S0022-328X(96)06738-1

M3 - Article

AN - SCOPUS:0031591248

SN - 0022-328X

VL - 536-537

SP - 433

EP - 436

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -