Antisymmetric exchange in the trinuclear clusters of copper (II)

B. S. Tsukerblat; B. Ya Kuyavskaya; M. I. Belinskii; A. V. Ablov; V. M. Novotortsev; V. T. Kalinnikov

doi:10.1007/BF00581470

Antisymmetric exchange in the trinuclear clusters of copper (II)

B. S. Tsukerblat, B. Ya Kuyavskaya, M. I. Belinskii, A. V. Ablov, V. M. Novotortsev, V. T. Kalinnikov

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

The magnetic susceptibility of Cu₃(C₆H₅N₂O)₃(OH)SO₄ · 10.5 H₂O crystals was measured in the temperature interval 4.2-11 K and magnetic field range 0-50 kOe. The theoretical analysis of the effects of antisymmetric exchange was performed. An adequate interpretation of the experimental results may be done in terms of an antisymmetric exchange which is about 12 cm^-1 in the crystals discussed. The rhombic distortions of the trigonal cluster were shown to reduce the antisymmetric exchange.

Original language	English
Pages (from-to)	131-138
Number of pages	8
Journal	Theoretica Chimica Acta
Volume	38
Issue number	2
DOIs	https://doi.org/10.1007/BF00581470
State	Published - 1 Jun 1975
Externally published	Yes

Keywords

Copper (II)
Exchange interaction
Magnetic susceptibility

ASJC Scopus subject areas

Chiropractic

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10.1007/BF00581470

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@article{145556eb5f4e43ae861d87de41e24ac6,

title = "Antisymmetric exchange in the trinuclear clusters of copper (II)",

abstract = "The magnetic susceptibility of Cu3(C6H5N2O)3(OH)SO4 · 10.5 H2O crystals was measured in the temperature interval 4.2-11 K and magnetic field range 0-50 kOe. The theoretical analysis of the effects of antisymmetric exchange was performed. An adequate interpretation of the experimental results may be done in terms of an antisymmetric exchange which is about 12 cm-1 in the crystals discussed. The rhombic distortions of the trigonal cluster were shown to reduce the antisymmetric exchange.",

keywords = "Copper (II), Exchange interaction, Magnetic susceptibility",

author = "Tsukerblat, {B. S.} and Kuyavskaya, {B. Ya} and Belinskii, {M. I.} and Ablov, {A. V.} and Novotortsev, {V. M.} and Kalinnikov, {V. T.}",

year = "1975",

month = jun,

day = "1",

doi = "10.1007/BF00581470",

language = "English",

volume = "38",

pages = "131--138",

journal = "Theoretica Chimica Acta",

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TY - JOUR

T1 - Antisymmetric exchange in the trinuclear clusters of copper (II)

AU - Tsukerblat, B. S.

AU - Kuyavskaya, B. Ya

AU - Belinskii, M. I.

AU - Ablov, A. V.

AU - Novotortsev, V. M.

AU - Kalinnikov, V. T.

PY - 1975/6/1

Y1 - 1975/6/1

N2 - The magnetic susceptibility of Cu3(C6H5N2O)3(OH)SO4 · 10.5 H2O crystals was measured in the temperature interval 4.2-11 K and magnetic field range 0-50 kOe. The theoretical analysis of the effects of antisymmetric exchange was performed. An adequate interpretation of the experimental results may be done in terms of an antisymmetric exchange which is about 12 cm-1 in the crystals discussed. The rhombic distortions of the trigonal cluster were shown to reduce the antisymmetric exchange.

AB - The magnetic susceptibility of Cu3(C6H5N2O)3(OH)SO4 · 10.5 H2O crystals was measured in the temperature interval 4.2-11 K and magnetic field range 0-50 kOe. The theoretical analysis of the effects of antisymmetric exchange was performed. An adequate interpretation of the experimental results may be done in terms of an antisymmetric exchange which is about 12 cm-1 in the crystals discussed. The rhombic distortions of the trigonal cluster were shown to reduce the antisymmetric exchange.

KW - Copper (II)

KW - Exchange interaction

KW - Magnetic susceptibility

UR - http://www.scopus.com/inward/record.url?scp=0000791140&partnerID=8YFLogxK

U2 - 10.1007/BF00581470

DO - 10.1007/BF00581470

M3 - Article

AN - SCOPUS:0000791140

SN - 0040-5744

VL - 38

SP - 131

EP - 138

JO - Theoretica Chimica Acta

JF - Theoretica Chimica Acta

IS - 2

ER -

Antisymmetric exchange in the trinuclear clusters of copper (II)

Abstract

Keywords

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