Benzidine: A co-crystallization agent for proton acceptors

Michal Rafilovich; Joel Bernstein; Magali B. Hickey; Michael Tauber

doi:10.1021/cg0701325

Benzidine: A co-crystallization agent for proton acceptors

Michal Rafilovich, Joel Bernstein, Magali B. Hickey, Michael Tauber

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The search for co-crystals of amines as bifunctional hydrogen-bond donors with bidentate oxygens as bifunctional hydrogen-bond acceptors, as part of a program to investigate the utility of using the R₄² (8) hydrogen-bonding motif, has yielded three co-crystals of benzidine with p-benzoquinone, diphenyl sulfoxide, and triphenylphosphine oxide. The crystal structures for all three materials are reported. Only the co-crystal structure of benzidine/diphenyl sulfoxide/water reveals the desired motif.

Original language	English
Pages (from-to)	1777-1782
Number of pages	6
Journal	Crystal Growth and Design
Volume	7
Issue number	9
DOIs	https://doi.org/10.1021/cg0701325
State	Published - 1 Sep 2007

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1021/cg0701325

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abstract = "The search for co-crystals of amines as bifunctional hydrogen-bond donors with bidentate oxygens as bifunctional hydrogen-bond acceptors, as part of a program to investigate the utility of using the R42 (8) hydrogen-bonding motif, has yielded three co-crystals of benzidine with p-benzoquinone, diphenyl sulfoxide, and triphenylphosphine oxide. The crystal structures for all three materials are reported. Only the co-crystal structure of benzidine/diphenyl sulfoxide/water reveals the desired motif.",

author = "Michal Rafilovich and Joel Bernstein and Hickey, {Magali B.} and Michael Tauber",

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T2 - A co-crystallization agent for proton acceptors

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AU - Bernstein, Joel

AU - Hickey, Magali B.

AU - Tauber, Michael

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N2 - The search for co-crystals of amines as bifunctional hydrogen-bond donors with bidentate oxygens as bifunctional hydrogen-bond acceptors, as part of a program to investigate the utility of using the R42 (8) hydrogen-bonding motif, has yielded three co-crystals of benzidine with p-benzoquinone, diphenyl sulfoxide, and triphenylphosphine oxide. The crystal structures for all three materials are reported. Only the co-crystal structure of benzidine/diphenyl sulfoxide/water reveals the desired motif.

AB - The search for co-crystals of amines as bifunctional hydrogen-bond donors with bidentate oxygens as bifunctional hydrogen-bond acceptors, as part of a program to investigate the utility of using the R42 (8) hydrogen-bonding motif, has yielded three co-crystals of benzidine with p-benzoquinone, diphenyl sulfoxide, and triphenylphosphine oxide. The crystal structures for all three materials are reported. Only the co-crystal structure of benzidine/diphenyl sulfoxide/water reveals the desired motif.

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U2 - 10.1021/cg0701325

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JF - Crystal Growth and Design

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ER -

Benzidine: A co-crystallization agent for proton acceptors

Abstract

ASJC Scopus subject areas

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