Bias-Dependent Stability of Perovskite Solar Cells Studied Using Natural and Concentrated Sunlight

K. M. Anoop, Mark V. Khenkin, Francesco Di Giacomo, Yulia Galagan, Stav Rahmany, Lioz Etgar, Eugene A. Katz, Iris Visoly-Fisher

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Degradation rates in perovskite solar cells (PSCs) were previously shown to be bias dependent; however, little is known about the mechanisms and driving factors that account for such degradation. Herein, stability studies under concentrated sunlight are demonstrated as a powerful experimental methodology to investigate bias-dependent PSC degradation mechanisms. Stress testing of encapsulated PSCs' stability shows that light intensity is more significant than the illumination dose for PSC degradation under short-circuit (SC) conditions, whereas the dose is the determining factor under open-circuit (OC) stressing. This indicates that different degradation mechanisms are dominant under different bias conditions. It is postulated that degradation at SC biasing is dominated by ion migration, facilitated by photogenerated defects. Degradation at OC biasing can be explained by photogenerated radicals acting as nonradiative recombination centers (charge traps), which are created via reactions with accumulated charge carriers. Trap formation upon OC biasing is in accordance with degradation of photoluminescence and OC voltage (VOC) observed under this stress. A combination of multiple mechanisms, all with reduced driving forces compared with OC /SC biasing, explains degradation at maximum power point biasing. Understanding the bias effect on PSC stability can elucidate the underlying degradation mechanisms and lead to routes to reduce them.

Original languageEnglish
Article number1900335
JournalSolar RRL
Volume4
Issue number2
DOIs
StatePublished - 1 Feb 2020

Keywords

  • bias-induced degradation
  • perovskite solar cells
  • stability

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Energy Engineering and Power Technology
  • Electronic, Optical and Magnetic Materials
  • Electrical and Electronic Engineering

Fingerprint

Dive into the research topics of 'Bias-Dependent Stability of Perovskite Solar Cells Studied Using Natural and Concentrated Sunlight'. Together they form a unique fingerprint.

Cite this