Bromine and carbon isotope effects during photolysis of brominated phenols

Yevgeni Zakon, Ludwik Halicz, Faina Gelman

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

In the present study, carbon and bromine isotope effects during UV-photodegradation of bromophenols in aqueous and ethanolic solutions were determined. An anomalous relatively high inverse bromine isotope fractionation (εreactive position up to +5.1‰) along with normal carbon isotope effect (εreactive position of -12.6‰ to -23.4‰) observed in our study may be attributed to coexistence of both mass-dependent and mass-independent isotope fractionation of C-Br bond cleavage. Isotope effects of a similar scale were observed for all the studied reactions in ethanol, and for 4-bromophenol in aqueous solution. This may point out related radical mechanism for these processes. The lack of any carbon and bromine isotope effects during photodegradation of 2-bromophenol in aqueous solution possibly indicates that C-Br bond cleavage is not a rate-limiting step in the reaction. The bromine isotope fractionation, without any detectable carbon isotope effect, that was observed for 3-bromophenol photolysis in aqueous solution probably originates from mass-independent fractionation.

Original languageEnglish
Pages (from-to)14147-14153
Number of pages7
JournalEnvironmental Science and Technology
Volume47
Issue number24
DOIs
StatePublished - 17 Dec 2013
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • Environmental Chemistry

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