Abstract
This chapter presents a methodology to assess the quality of experimental vapour–liquid equilibrium data for binary systems through so-called thermodynamic consistency tests. Several methods that have been described in the literature and a new contribution made by the authors are presented together with a description of each method. These methods were applied to several binary systems extracted from the literature in order to assess their quality and draw conclusions. A practical example is carried out on unpublished experimental data for a binary system.
Original language | English |
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Title of host publication | Gibbs Energy and Helmholtz Energy |
Subtitle of host publication | Liquids, Solutions and Vapours |
Editors | Emmerich Wilhelm, Trevor M Letcher |
Publisher | Royal Society of Chemistry |
Chapter | 7 |
Pages | 238-268 |
Number of pages | 31 |
Edition | 1 |
ISBN (Print) | 1839162015, 978-1839162015 |
DOIs | |
State | Published - 15 Sep 2021 |