Catalysis in a porous molecular capsule: Activation by regulated access to sixty metal centers spanning a truncated icosahedron

Keyphrases

• Acetate 50%
• Acetate Ligand 16%
• Acetate-free 16%
• Acid Property 16%
• Activation Parameters 16%
• Active Sites 16%
• Brønsted Acid 16%
• Catalytic Cycle 16%
• Catalytic Transformation 16%
• Cleavage Rate 16%
• Deuterium 16%
• DFT Calculations 16%
• Ether Cleavage 33%
• Ether Oxygen 16%
• First-order 16%
• Hydrogen Peroxide 66%
• Isobutene 50%
• Kinetic Data 16%
• Labeling Experiment 16%
• Lewis Acids 16%
• Lines of Evidence 16%
• Linker 33%
• Metal Center 100%
• Methyl Tert-butyl Ether 66%
• Microenvironment 16%
• Microscopic Reversibility 16%
• Mo(V) 100%
• Mo(VI) 50%
• Molecular Capsules 100%
• Molybdenum Oxide 16%
• Nanoreactor 16%
• Negatively Charged 16%
• Organic Guests 16%
• Organic Substrate 16%
• Oxide-based 16%
• Oxygen-18 16%
• Porous Metal Oxides 16%
• Regulated Access 100%
• Reverse Reaction 16%
• Spherical Capsule 16%
• Truncated Icosahedron 100%
• Water-soluble 16%
• Well-behaved 16%

Chemistry

• Deetherification 50%
• Density Functional Theory 25%
• Deuterium(.) 25%
• Kinetics Type 25%
• Metal Oxide 25%
• Methyl Tert-Butyl Ether 100%
• Molybdenum Oxide 25%
• Nanoreactors 25%
• Porosity 100%
• Water Soluble 25%