Catalysis of ligand exchange in uranyl complexes in non-aqueous solvents

Yair Egozy; Shmuel Weiss

doi:10.1016/0022-1902(76)80146-7

Catalysis of ligand exchange in uranyl complexes in non-aqueous solvents

Yair Egozy, Shmuel Weiss

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Catalysis of the exchange reaction between TBP and diphenyl carbazone, as ligands bound to uranyl, as well as catalysis of exchange between bound and free TBP was studied in a number of solvents. Catalysts were alcohols and water. A mechanism for the catalytic action is proposed and rate constants are reported. The implication of the results to the mechanism of uranium transfer through solvent membranes is discussed.

Original language	English
Pages (from-to)	1335-1337
Number of pages	3
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	38
Issue number	7
DOIs	https://doi.org/10.1016/0022-1902(76)80146-7
State	Published - 1 Jan 1976
Externally published	Yes

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title = "Catalysis of ligand exchange in uranyl complexes in non-aqueous solvents",

abstract = "Catalysis of the exchange reaction between TBP and diphenyl carbazone, as ligands bound to uranyl, as well as catalysis of exchange between bound and free TBP was studied in a number of solvents. Catalysts were alcohols and water. A mechanism for the catalytic action is proposed and rate constants are reported. The implication of the results to the mechanism of uranium transfer through solvent membranes is discussed.",

author = "Yair Egozy and Shmuel Weiss",

year = "1976",

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doi = "10.1016/0022-1902(76)80146-7",

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AU - Egozy, Yair

AU - Weiss, Shmuel

PY - 1976/1/1

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N2 - Catalysis of the exchange reaction between TBP and diphenyl carbazone, as ligands bound to uranyl, as well as catalysis of exchange between bound and free TBP was studied in a number of solvents. Catalysts were alcohols and water. A mechanism for the catalytic action is proposed and rate constants are reported. The implication of the results to the mechanism of uranium transfer through solvent membranes is discussed.

AB - Catalysis of the exchange reaction between TBP and diphenyl carbazone, as ligands bound to uranyl, as well as catalysis of exchange between bound and free TBP was studied in a number of solvents. Catalysts were alcohols and water. A mechanism for the catalytic action is proposed and rate constants are reported. The implication of the results to the mechanism of uranium transfer through solvent membranes is discussed.

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U2 - 10.1016/0022-1902(76)80146-7

DO - 10.1016/0022-1902(76)80146-7

M3 - Article

AN - SCOPUS:49349134404

SN - 0022-1902

VL - 38

SP - 1335

EP - 1337

JO - Journal of Inorganic and Nuclear Chemistry

JF - Journal of Inorganic and Nuclear Chemistry

IS - 7

ER -

Catalysis of ligand exchange in uranyl complexes in non-aqueous solvents

Abstract

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