Catalysis of ligand exchange in uranyl complexes in non-aqueous solvents

Yair Egozy, Shmuel Weiss

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Catalysis of the exchange reaction between TBP and diphenyl carbazone, as ligands bound to uranyl, as well as catalysis of exchange between bound and free TBP was studied in a number of solvents. Catalysts were alcohols and water. A mechanism for the catalytic action is proposed and rate constants are reported. The implication of the results to the mechanism of uranium transfer through solvent membranes is discussed.

Original languageEnglish
Pages (from-to)1335-1337
Number of pages3
JournalJournal of Inorganic and Nuclear Chemistry
Volume38
Issue number7
DOIs
StatePublished - 1 Jan 1976
Externally publishedYes

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