Catalysis of Oxygen Cathodic Reduction by Adsorbed Iron(111)-Tetra (N,N,N-Trimethylanilinium) Porphyrin on Glassy Carbon Electrodes

Armand Bettelheim; Rachel Parash; Dan Ozer

doi:10.1149/1.2123484

Catalysis of Oxygen Cathodic Reduction by Adsorbed Iron(111)-Tetra (N,N,N-Trimethylanilinium) Porphyrin on Glassy Carbon Electrodes

Armand Bettelheim
, Rachel Parash
, Dan Ozer

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The adsorption of iron(111)-tetra (N,N,N-trimethylanilinium) porphyrin on glassy carbon was studied in aqueous solutions using cyclic voltammetry, differential pulse voltammetry, chronoamperometry, and the RRDE technique. The porphyrin was found to catalyze oxygen electroreduction; the overpotential is reduced by about 400 mV and the hydrogen peroxide yield is ≃ 5% compared to ≃ 25% in the absence of catalyst.

Original language	English
Pages (from-to)	2247-2250
Number of pages	4
Journal	Journal of the Electrochemical Society
Volume	129
Issue number	10
DOIs	https://doi.org/10.1149/1.2123484
State	Published - 1 Jan 1982
Externally published	Yes

Keywords

chemlsorption
gas
organic
voltammetry

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

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10.1149/1.2123484

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title = "Catalysis of Oxygen Cathodic Reduction by Adsorbed Iron(111)-Tetra (N,N,N-Trimethylanilinium) Porphyrin on Glassy Carbon Electrodes",

abstract = "The adsorption of iron(111)-tetra (N,N,N-trimethylanilinium) porphyrin on glassy carbon was studied in aqueous solutions using cyclic voltammetry, differential pulse voltammetry, chronoamperometry, and the RRDE technique. The porphyrin was found to catalyze oxygen electroreduction; the overpotential is reduced by about 400 mV and the hydrogen peroxide yield is ≃ 5\% compared to ≃ 25\% in the absence of catalyst.",

keywords = "chemlsorption, gas, organic, voltammetry",

author = "Armand Bettelheim and Rachel Parash and Dan Ozer",

year = "1982",

month = jan,

day = "1",

doi = "10.1149/1.2123484",

language = "English",

volume = "129",

pages = "2247--2250",

journal = "Journal of the Electrochemical Society",

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publisher = "Institute of Physics",

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TY - JOUR

T1 - Catalysis of Oxygen Cathodic Reduction by Adsorbed Iron(111)-Tetra (N,N,N-Trimethylanilinium) Porphyrin on Glassy Carbon Electrodes

AU - Bettelheim, Armand

AU - Parash, Rachel

AU - Ozer, Dan

PY - 1982/1/1

Y1 - 1982/1/1

N2 - The adsorption of iron(111)-tetra (N,N,N-trimethylanilinium) porphyrin on glassy carbon was studied in aqueous solutions using cyclic voltammetry, differential pulse voltammetry, chronoamperometry, and the RRDE technique. The porphyrin was found to catalyze oxygen electroreduction; the overpotential is reduced by about 400 mV and the hydrogen peroxide yield is ≃ 5% compared to ≃ 25% in the absence of catalyst.

AB - The adsorption of iron(111)-tetra (N,N,N-trimethylanilinium) porphyrin on glassy carbon was studied in aqueous solutions using cyclic voltammetry, differential pulse voltammetry, chronoamperometry, and the RRDE technique. The porphyrin was found to catalyze oxygen electroreduction; the overpotential is reduced by about 400 mV and the hydrogen peroxide yield is ≃ 5% compared to ≃ 25% in the absence of catalyst.

KW - chemlsorption

KW - gas

KW - organic

KW - voltammetry

UR - https://www.scopus.com/pages/publications/0020201551

U2 - 10.1149/1.2123484

DO - 10.1149/1.2123484

M3 - Article

AN - SCOPUS:0020201551

SN - 0013-4651

VL - 129

SP - 2247

EP - 2250

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

IS - 10

ER -

Catalysis of Oxygen Cathodic Reduction by Adsorbed Iron(111)-Tetra (N,N,N-Trimethylanilinium) Porphyrin on Glassy Carbon Electrodes

Abstract

Keywords

ASJC Scopus subject areas

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