Catena-Poly[bis(tert-butylammonium) [plumbate(II)-tri-μ-iodo] iodide dihydrate]

David G. Billing; A. Lemmerer

doi:10.1107/S0108270106016167

Catena-Poly[bis(tert-butylammonium) [plumbate(II)-tri-μ-iodo] iodide dihydrate]

David G. Billing, A. Lemmerer

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The title compound, {(C₄H₁₂N)₂[PbI ₃]I·2H₂O}_n, crystallizes as an organic-inorganic hybrid. The six-coordinate Pb atom lies on a centre of inversion and all the I atoms lie on mirror planes; the two independent cations both lie across mirror planes. The structure contains anionic chains along [100] of fused [PbI₃]^- units forming face-sharing octahedra. Four cations enclose channels occupied by isolated iodide ions and water molecules of hydration.

Original language	English
Pages (from-to)	m264-m266
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	62
Issue number	6
DOIs	https://doi.org/10.1107/S0108270106016167
State	Published - 1 Jun 2006
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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title = "Catena-Poly[bis(tert-butylammonium) [plumbate(II)-tri-μ-iodo] iodide dihydrate]",

abstract = "The title compound, \{(C4H12N)2[PbI 3]I·2H2O\}n, crystallizes as an organic-inorganic hybrid. The six-coordinate Pb atom lies on a centre of inversion and all the I atoms lie on mirror planes; the two independent cations both lie across mirror planes. The structure contains anionic chains along [100] of fused [PbI3]- units forming face-sharing octahedra. Four cations enclose channels occupied by isolated iodide ions and water molecules of hydration.",

author = "Billing, \{David G.\} and A. Lemmerer",

year = "2006",

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doi = "10.1107/S0108270106016167",

language = "English",

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publisher = "John Wiley \& Sons Inc.",

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T1 - Catena-Poly[bis(tert-butylammonium) [plumbate(II)-tri-μ-iodo] iodide dihydrate]

AU - Billing, David G.

AU - Lemmerer, A.

PY - 2006/6/1

Y1 - 2006/6/1

N2 - The title compound, {(C4H12N)2[PbI 3]I·2H2O}n, crystallizes as an organic-inorganic hybrid. The six-coordinate Pb atom lies on a centre of inversion and all the I atoms lie on mirror planes; the two independent cations both lie across mirror planes. The structure contains anionic chains along [100] of fused [PbI3]- units forming face-sharing octahedra. Four cations enclose channels occupied by isolated iodide ions and water molecules of hydration.

AB - The title compound, {(C4H12N)2[PbI 3]I·2H2O}n, crystallizes as an organic-inorganic hybrid. The six-coordinate Pb atom lies on a centre of inversion and all the I atoms lie on mirror planes; the two independent cations both lie across mirror planes. The structure contains anionic chains along [100] of fused [PbI3]- units forming face-sharing octahedra. Four cations enclose channels occupied by isolated iodide ions and water molecules of hydration.

UR - https://www.scopus.com/pages/publications/33745174849

U2 - 10.1107/S0108270106016167

DO - 10.1107/S0108270106016167

M3 - Article

AN - SCOPUS:33745174849

SN - 0108-2701

VL - 62

SP - m264-m266

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

Catena-Poly[bis(tert-butylammonium) [plumbate(II)-tri-μ-iodo] iodide dihydrate]

Abstract

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