Cathodic electrosynthesis of PZT films

I. Zhitomirsky; A. Kohn; L. Gal-Or

doi:10.1016/0167-577X(95)00191-3

Cathodic electrosynthesis of PZT films

I. Zhitomirsky, A. Kohn, L. Gal-Or

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Cathodic electrosynthesis of lead zirconate titanate (PZT) films on platinum substrates was performed via hydrolysis by electrogenerated base of TiCl₄, ZrOCl₂ and Pb(NO₃)₂ salts dissolved in water in the presence of hydrogen peroxide. Possible cathodic reactions which underly the base formation and the role of hydrogen peroxide in the deposition process are discussed. Deposits as-obtained were amorphous and formation of a single perovskite phase was observed after annealing at 500 °C. By variation of current density and deposition time, the amount of the deposited material could be controlled. The films were characterized by XRD, TG/DTA and SEM.

Original language	English
Pages (from-to)	223-227
Number of pages	5
Journal	Materials Letters
Volume	25
Issue number	5-6
DOIs	https://doi.org/10.1016/0167-577X(95)00191-3
State	Published - 1 Jan 1995
Externally published	Yes

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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title = "Cathodic electrosynthesis of PZT films",

abstract = "Cathodic electrosynthesis of lead zirconate titanate (PZT) films on platinum substrates was performed via hydrolysis by electrogenerated base of TiCl4, ZrOCl2 and Pb(NO3)2 salts dissolved in water in the presence of hydrogen peroxide. Possible cathodic reactions which underly the base formation and the role of hydrogen peroxide in the deposition process are discussed. Deposits as-obtained were amorphous and formation of a single perovskite phase was observed after annealing at 500 °C. By variation of current density and deposition time, the amount of the deposited material could be controlled. The films were characterized by XRD, TG/DTA and SEM.",

author = "I. Zhitomirsky and A. Kohn and L. Gal-Or",

year = "1995",

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doi = "10.1016/0167-577X(95)00191-3",

language = "English",

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journal = "Materials Letters",

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T1 - Cathodic electrosynthesis of PZT films

AU - Zhitomirsky, I.

AU - Kohn, A.

AU - Gal-Or, L.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - Cathodic electrosynthesis of lead zirconate titanate (PZT) films on platinum substrates was performed via hydrolysis by electrogenerated base of TiCl4, ZrOCl2 and Pb(NO3)2 salts dissolved in water in the presence of hydrogen peroxide. Possible cathodic reactions which underly the base formation and the role of hydrogen peroxide in the deposition process are discussed. Deposits as-obtained were amorphous and formation of a single perovskite phase was observed after annealing at 500 °C. By variation of current density and deposition time, the amount of the deposited material could be controlled. The films were characterized by XRD, TG/DTA and SEM.

AB - Cathodic electrosynthesis of lead zirconate titanate (PZT) films on platinum substrates was performed via hydrolysis by electrogenerated base of TiCl4, ZrOCl2 and Pb(NO3)2 salts dissolved in water in the presence of hydrogen peroxide. Possible cathodic reactions which underly the base formation and the role of hydrogen peroxide in the deposition process are discussed. Deposits as-obtained were amorphous and formation of a single perovskite phase was observed after annealing at 500 °C. By variation of current density and deposition time, the amount of the deposited material could be controlled. The films were characterized by XRD, TG/DTA and SEM.

UR - http://www.scopus.com/inward/record.url?scp=0029483758&partnerID=8YFLogxK

U2 - 10.1016/0167-577X(95)00191-3

DO - 10.1016/0167-577X(95)00191-3

M3 - Article

AN - SCOPUS:0029483758

SN - 0167-577X

VL - 25

SP - 223

EP - 227

JO - Materials Letters

JF - Materials Letters

IS - 5-6

ER -

Cathodic electrosynthesis of PZT films

Abstract

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