Characterization of biopolymer pectin with lithium chloride and its applications to electrochemical devices

P. Perumal; P. Christopher Selvin; S. Selvasekarapandian

doi:10.1007/s11581-018-2507-5

Characterization of biopolymer pectin with lithium chloride and its applications to electrochemical devices

P. Perumal, P. Christopher Selvin, S. Selvasekarapandian

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

Natural anionic polysaccharide pectin-based flexible electrolyte with different compositions of LiCl has been prepared by solution casting technique. The prepared membranes have been characterized by X-ray Diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and AC complex impedance analysis. The pectin/LiCl (50:50 M.wt%) complex exhibits high ionic conductivity in the order of 2.08 × 10⁻³ S cm⁻¹. The temperature-dependent ionic conductivity obeys the Arrhenius behavior. The best performing membrane has been used to construct the primary lithium ion battery. The open-circuit voltage of the constructed primary lithium ion battery is found to be 1.93 V.

Original language	English
Pages (from-to)	3259-3270
Number of pages	12
Journal	Ionics
Volume	24
Issue number	10
DOIs	https://doi.org/10.1007/s11581-018-2507-5
State	Published - 1 Oct 2018
Externally published	Yes

Keywords

Amorphous nature
Battery
Conductivity
Lithium chloride
Pectin

ASJC Scopus subject areas

General Chemical Engineering
General Materials Science
General Engineering
General Physics and Astronomy

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1007/s11581-018-2507-5

Cite this

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title = "Characterization of biopolymer pectin with lithium chloride and its applications to electrochemical devices",

abstract = "Natural anionic polysaccharide pectin-based flexible electrolyte with different compositions of LiCl has been prepared by solution casting technique. The prepared membranes have been characterized by X-ray Diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and AC complex impedance analysis. The pectin/LiCl (50:50 M.wt%) complex exhibits high ionic conductivity in the order of 2.08 × 10−3 S cm−1. The temperature-dependent ionic conductivity obeys the Arrhenius behavior. The best performing membrane has been used to construct the primary lithium ion battery. The open-circuit voltage of the constructed primary lithium ion battery is found to be 1.93 V.",

keywords = "Amorphous nature, Battery, Conductivity, Lithium chloride, Pectin",

author = "P. Perumal and {Christopher Selvin}, P. and S. Selvasekarapandian",

note = "Publisher Copyright: {\textcopyright} 2018, Springer-Verlag GmbH Germany, part of Springer Nature.",

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doi = "10.1007/s11581-018-2507-5",

language = "English",

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T1 - Characterization of biopolymer pectin with lithium chloride and its applications to electrochemical devices

AU - Perumal, P.

AU - Christopher Selvin, P.

AU - Selvasekarapandian, S.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Natural anionic polysaccharide pectin-based flexible electrolyte with different compositions of LiCl has been prepared by solution casting technique. The prepared membranes have been characterized by X-ray Diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and AC complex impedance analysis. The pectin/LiCl (50:50 M.wt%) complex exhibits high ionic conductivity in the order of 2.08 × 10−3 S cm−1. The temperature-dependent ionic conductivity obeys the Arrhenius behavior. The best performing membrane has been used to construct the primary lithium ion battery. The open-circuit voltage of the constructed primary lithium ion battery is found to be 1.93 V.

AB - Natural anionic polysaccharide pectin-based flexible electrolyte with different compositions of LiCl has been prepared by solution casting technique. The prepared membranes have been characterized by X-ray Diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and AC complex impedance analysis. The pectin/LiCl (50:50 M.wt%) complex exhibits high ionic conductivity in the order of 2.08 × 10−3 S cm−1. The temperature-dependent ionic conductivity obeys the Arrhenius behavior. The best performing membrane has been used to construct the primary lithium ion battery. The open-circuit voltage of the constructed primary lithium ion battery is found to be 1.93 V.

KW - Amorphous nature

KW - Battery

KW - Conductivity

KW - Lithium chloride

KW - Pectin

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DO - 10.1007/s11581-018-2507-5

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JO - Ionics

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Characterization of biopolymer pectin with lithium chloride and its applications to electrochemical devices

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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