Charge ordering in mixed-valence coordination compounds

S. I. Klokishner; B. S. Tsukerblat

doi:10.1016/0301-0104(88)85002-X

Charge ordering in mixed-valence coordination compounds

S. I. Klokishner, B. S. Tsukerblat

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Charge ordering in mixed-valence molecular crystals is predicted. It is shown that in such systems, depending on intramolecular parameters of electron transfer and exchange interaction, one or two phase transitions are possible. An anomalous temperature behaviour of the magnetic moment of charge-ordered crystals is predicted.

Original language	English
Pages (from-to)	11-20
Number of pages	10
Journal	Chemical Physics
Volume	125
Issue number	1
DOIs	https://doi.org/10.1016/0301-0104(88)85002-X
State	Published - 15 Sep 1988
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0301-0104(88)85002-X

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title = "Charge ordering in mixed-valence coordination compounds",

abstract = "Charge ordering in mixed-valence molecular crystals is predicted. It is shown that in such systems, depending on intramolecular parameters of electron transfer and exchange interaction, one or two phase transitions are possible. An anomalous temperature behaviour of the magnetic moment of charge-ordered crystals is predicted.",

author = "Klokishner, {S. I.} and Tsukerblat, {B. S.}",

year = "1988",

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doi = "10.1016/0301-0104(88)85002-X",

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T1 - Charge ordering in mixed-valence coordination compounds

AU - Klokishner, S. I.

AU - Tsukerblat, B. S.

PY - 1988/9/15

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N2 - Charge ordering in mixed-valence molecular crystals is predicted. It is shown that in such systems, depending on intramolecular parameters of electron transfer and exchange interaction, one or two phase transitions are possible. An anomalous temperature behaviour of the magnetic moment of charge-ordered crystals is predicted.

AB - Charge ordering in mixed-valence molecular crystals is predicted. It is shown that in such systems, depending on intramolecular parameters of electron transfer and exchange interaction, one or two phase transitions are possible. An anomalous temperature behaviour of the magnetic moment of charge-ordered crystals is predicted.

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U2 - 10.1016/0301-0104(88)85002-X

DO - 10.1016/0301-0104(88)85002-X

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VL - 125

SP - 11

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JO - Chemical Physics

JF - Chemical Physics

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ER -

Charge ordering in mixed-valence coordination compounds

Abstract

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